(N-isonicotinoyl-N'-thiobenzoylhydrazine)2 nickel(II) dichloride | 440106-99-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: (N-isonicotinoyl-N'-thiobenzoylhydrazine)2 nickel(II) dichloride
• 英文别名: N'-(benzenecarbonothioyl)pyridine-4-carbohydrazide;dichloronickel
• CAS: 440106-99-0
• 化学式: C₂₆H₂₂Cl₂N₆NiO₂S₂
• 分子量: 644.228
• InChiKey: AYWZFEBSZOUVJZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  nickel(II) chloride hexahydrate 、 N-isonicotinoyl-N'-thiobenzoylhydrazine 在 HCl 作用下， 以 甲醇 为溶剂， 以55%的产率得到(N-isonicotinoyl-N'-thiobenzoylhydrazine)2 nickel(II) dichloride
  参考文献：
  名称：

  SYNTHESIS, SPECTROSCOPIC CHARACTERIZATION, AND BIOLOGICAL ACTIVITY OF N-ISONICOTINOYL- N′-THIOBENZOYLHYDRAZINE COMPLEXES OF Co(II), Ni(II), Cu(II), AND Zn(II)

  摘要：

  A new ligand, N-isonicotinoyl-N'-thiobenzoylhydrazine (HINTB), has been prepared by the reaction of isonicotinic acid hydrazide and carboxymethyl dithiobenzoate. The addition complexes [M(HINTB)(2)Cl-2] [M = Co(II), Ni(II), Zn(II)], [Cu(HINTB)Cl-2], M(HINTB)(2)(CH3COO)(2) [M = Co(II), Ni(II)] and deprotonated complexes [Cu(INTB)(CH3COO)] and [Zn(INTB)(2)] have been prepared and characterized by elemental analyses, magnetic susceptibility, electronic, NMR and IR spectral data. The room temperature ESR spectra of [Cu(HINTB)Cl-2] [Cu(INTB)(CH3COO)] are characteristic of monomeric and dimeric species, respectively. The ligand and the complexes have been screened for activity against a number of fungi and bacteria.

  DOI：

  10.1081/sim-120003203