[cobalt(II)(2,3-dioxo-5,6;13,14-dibenzo-7,12-dimethyl-1,4,8,11-tetraazacyclotetradeca-7,11-diene-2H)] | 1391034-11-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [cobalt(II)(2,3-dioxo-5,6;13,14-dibenzo-7,12-dimethyl-1,4,8,11-tetraazacyclotetradeca-7,11-diene-2H)]
• CAS: 1391034-11-9
• 化学式: C₂₀H₁₈CoN₄O₂
• 分子量: 405.382
• InChiKey: BBPXQJACNAMHGQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  水 、 cobalt(II) perchlorate hexahydrate 、 [cobalt(II)(2,3-dioxo-5,6;13,14-dibenzo-7,12-dimethyl-1,4,8,11-tetraazacyclotetradeca-7,11-diene-2H)] 、 sodium azide 以 乙醇 为溶剂， 以44%的产率得到[cobalt(III)(2,3-dioxo-5,6;13,14-dibenzo-7,12-dimethyl-1,4,8,11-tetraazacyclotetradeca-7,11-diene-2H)(N3)2)2Co(ethanol)2]*2H2O
  参考文献：
  名称：

  Synthesis and crystal structures of the first cobalt complexes of macrocyclic oxamido

  摘要：

  One novel macrocyclic oxamido-cobalt (II) complex CoL (H2L = 2,3-dioxo-5,6; 13,14-dibenzo-7,12-dimethyl-1,4,8,11-tetraazacyclotetradeca-7,11-diene) (1) has been synthesized solvothermally and characterized by X-ray diffraction analysis. By using the mononuclear cobalt complex as a building block and N-3 as auxiliary groups, a trinuclear complex (CoL)(2)Mn(N-3)(4)center dot 2H2O (2) and two one-dimensional complexes (CoL)(2)Cd(N-3)(4)center dot 2H2O (3), (CoL)(2)Co(N-3)(4)center dot 2H2O (4) have been prepared by stepwise synthesis and characterized. The structure of complex 1 consists of a neutral cobalt (II) complex of the [14] N-4 macrocyclic oxamido dianion. In complex 2, the center manganese (II) ion is in a slightly distorted octahedral environment and N-3 groups only act as terminal ligands. Complex 3 and 4 are similar in structure and both show a one-dimensional chain structure via oxamido and N-3 ligands. N-3 ligands show two kinds of coordination mode. In complex 2-4, cobalt ion in the ring is trivalence. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.04.022
• 作为产物：
  描述：

  2,2'-(oxalyldiimino)bis(acetophenone) 、 cobalt(II) diacetate tetrahydrate 、 乙二胺 以 乙醇 为溶剂， 以93%的产率得到[cobalt(II)(2,3-dioxo-5,6;13,14-dibenzo-7,12-dimethyl-1,4,8,11-tetraazacyclotetradeca-7,11-diene-2H)]
  参考文献：
  名称：

  Synthesis and crystal structures of the first cobalt complexes of macrocyclic oxamido

  摘要：

  One novel macrocyclic oxamido-cobalt (II) complex CoL (H2L = 2,3-dioxo-5,6; 13,14-dibenzo-7,12-dimethyl-1,4,8,11-tetraazacyclotetradeca-7,11-diene) (1) has been synthesized solvothermally and characterized by X-ray diffraction analysis. By using the mononuclear cobalt complex as a building block and N-3 as auxiliary groups, a trinuclear complex (CoL)(2)Mn(N-3)(4)center dot 2H2O (2) and two one-dimensional complexes (CoL)(2)Cd(N-3)(4)center dot 2H2O (3), (CoL)(2)Co(N-3)(4)center dot 2H2O (4) have been prepared by stepwise synthesis and characterized. The structure of complex 1 consists of a neutral cobalt (II) complex of the [14] N-4 macrocyclic oxamido dianion. In complex 2, the center manganese (II) ion is in a slightly distorted octahedral environment and N-3 groups only act as terminal ligands. Complex 3 and 4 are similar in structure and both show a one-dimensional chain structure via oxamido and N-3 ligands. N-3 ligands show two kinds of coordination mode. In complex 2-4, cobalt ion in the ring is trivalence. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.04.022