1-phenyl-N-[2-[2-(1-phenylethylideneamino)phenyl]sulfanylphenyl]ethanimine | 516484-53-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-phenyl-N-[2-[2-(1-phenylethylideneamino)phenyl]sulfanylphenyl]ethanimine
• CAS: 516484-53-0
• 化学式: C₂₈H₂₄N₂S
• 分子量: 420.578
• InChiKey: LHSZKCLYDUKXAR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7
• 重原子数：
  31
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  50
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  trichlorotritetrahydrofuran chromium(III) 、 1-phenyl-N-[2-[2-(1-phenylethylideneamino)phenyl]sulfanylphenyl]ethanimine 以 四氢呋喃 为溶剂， 以84%的产率得到
  参考文献：
  名称：

  Syntheses of chromium(III) complexes with Schiff-base ligands and their catalytic behaviors for ethylene polymerization

  摘要：

  A series of chromium(III) complexes LCrCl3 (4a-c) bearing chelating 2,2'-iminodiphenyisulfide ligands [L = (2-ArMeC=NAr)(2)S] was synthesized in good yields from the corresponding ligands and CrCl3.(THF). Using modified methylaluminoxane (MMAO) as a cocatalyst, these complexes display moderate activities towards ethylene polymerization, and produce highly linear polyethylenes with broad molecular weight distribution. Polymer yields, catalyst activities and the molecular weights, as well as the molecular weight distributions of the polymers can be controlled over a wide range by the variation of the structures of the chromium(III) complexes and the polymerization parameters, such as Al/Cr molar ratio, reaction temperature and ethylene pressure. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2005.08.060