[Ho(5-(2-pyridyl)tetrazolate)3(H2O)4]*H2O | 960590-91-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 英文名称: [Ho(5-(2-pyridyl)tetrazolate)3(H2O)4]*H2O
• CAS: 960590-91-4
• 化学式: C₁₈H₂₀HoN₁₅O₄*H₂O
• 分子量: 693.401
• InChiKey: CPMGHXSPNFZVKI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [Ho(5-(2-pyridyl)tetrazolate)2(H2O)4]Cl 、 水 以 水 为溶剂， 生成 [Ho(5-(2-pyridyl)tetrazolate)3(H2O)4]*H2O
  参考文献：
  名称：

  Synthesis and structural characterisation of cationic, neutral and hydroxo-bridged lanthanoid (La, Gd, Ho, Yb, Y) bis 5-(2-pyridyl)tetrazolate complexes

  摘要：

  Reaction of an excess of hydrated LnCl(3) (Ln = La, Gd, Ho, Yb, Y) with sodium 5-(2-pyridyl)tetrazolate (Napytz) in water led to the formation of either cationic disubstituted complexes (La, Gd, Ho) or neutral g-hydroxo-bridged dimers (Y, Yb). Interestingly, there is a lack of propensity for these disubstituted complexes to redistribute forming trisubstituted ones, which is a common behaviour in lanthanoid chemistry. Also, compared to their corresponding lanthanoid carboxylates, all these products are discrete molecular entities forming an extensive hydrogen-bonded and/or pi stacking network rather than hybrid polymeric frameworks. (C) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.08.017