[PtCl2*3-aminopropyl(phenyl)telluride] | 166830-88-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [PtCl2*3-aminopropyl(phenyl)telluride]
• 英文别名: dichloroplatinum;3-phenyltellanylpropan-1-amine
• CAS: 166830-88-2
• 化学式: C₉H₁₃Cl₂NPtTe
• 分子量: 528.795
• InChiKey: KVBDPXBFJOAWEW-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  potassium tetrachloroplatinate(II) 、 3-(phenyltelluryl)propane-1-amine 以 乙醇 、 水 、 丙酮 为溶剂， 以80%的产率得到[PtCl2*3-aminopropyl(phenyl)telluride]
  参考文献：
  名称：

  Synthesis and multinuclear NMR studies of 3-aminopropyl(aryl)chalcogenides, NH2CH2CH2CH2EAr (E = Se, Te), and their complexes with Pt(II) and Pd(II)

  摘要：

  The asymmetric ligands, 3-aminopropyl(aryl)tellurides (1a, 1b) [Ar = Ph (a); C6H4-OMe (b)] and 3-aminopropyl(phenyl)selenide (2) and their complexes with platinum(II) and palladium(II), viz. [PtCl2(1a, 1b)] (3, 4), [PtCl2(2)] (5), [PdCl2(1a, 1b)] (6, 7), [PdCl2(2)] (8), [(Me)ClPd(1b)] (9) and [(Me)ClPd(1b)(2)](10) have been made and characterized. Complexes 3-8, have square planar geometry around the metal (Pd or Pt) with the (Te,N)- or (Se,N)-ligand coordinated in a bidentate mode and the two chlorines cis to each other. Complex 9 also has a square planar geometry, with Me trans to nitrogen and Cl trans to tellurium. In complex 10 where Pd appears to be in a square planar geometry the two tellurium atoms are judged to be trans to each other.

  DOI：

  10.1016/0022-328x(95)05403-c