| 1021488-07-2

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• CAS: 1021488-07-2
• 化学式: C₃₀H₂₆N₂NiO₂S₆
• 分子量: 697.635
• InChiKey: AIJHTFFSPAKJOK-UIEZAYFCSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  nickel(II) acetate tetrahydrate 、 HOC₆H₄CHNC₇H₂S₂CS₂C₂(SC₃H₇)2NCHC₆H₄OH 以 二氯甲烷 、 乙腈 为溶剂， 以88%的产率得到
  参考文献：
  名称：

  Coordination Chemistry of a π-Extended, Rigid and Redox-Active Tetrathiafulvalene-Fused Schiff-Base Ligand

  摘要：

  A pi-extended, redox-active tetradentate tetrathiafulvalene-fused salphen [salphen = N,N'-phenylenebis(salicylideneimine)] compound (L) was prepared via a direct Schiff-base condensation of the corresponding diaminetetrathiafulvalene (TTF) precursor with salicylaldehyde. Its chelating coordination ability has been demonstrated by the formation of the corresponding transition metal complexes in the presence of M(OAc)(2) center dot nH(2)O (M = CO(II), Ni(II), Cu(II)) and FeCl3 center dot 6H(2)O, Three complexes have been characterized by single-crystal X-ray diffraction analysis showing that the TTF-salphen ligand coordinates to the metal ions in a planar mode through the nitrogen and oxygen atoms in a N2O2 cis-configuration. In the case of Fe(III), a dinuclear oxo-bridged Fe(III) complex is formed. These paramagnetic complexes are promising building blocks for the construction of dual functional materials due to their unique structural features (planarity and rigidity) as well as their inherent redox properties.

  DOI：

  10.1021/ic800138x