bis(2-aminothiophenol)dibenzoylmethimine | 367501-50-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯硫酚类
• 英文名称: bis(2-aminothiophenol)dibenzoylmethimine
• 英文别名: 2-HSC6H4NCPhCH2C(C6H5)NC6H4SH-2；2-[[1,3-Diphenyl-3-(2-sulfanylphenyl)iminopropylidene]amino]benzenethiol
• CAS: 367501-50-6
• 化学式: C₂₇H₂₂N₂S₂
• 分子量: 438.617
• InChiKey: CKTUTNVCVPMSIC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  31
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  26.7
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  bis(2-aminothiophenol)dibenzoylmethimine 、 三苯基锑 以 苯 为溶剂， 以82%的产率得到(2-SC6H4NCPhCH2C(C6H5)NC6H4S-2)SbPh
  参考文献：
  名称：

  SYNTHESIS AND CHARACTERIZATION OF SOME NEW MONOPHENYLANTIMONY(III) DERIVATIVES OF BIFUNCTIONAL TETRADENTATE LIGANDS

  摘要：

  Monophenylantimony(III) derivatives of bifunctional tetradentate ligands having the general formula PhSb[RC(NC6H4S)CH2 (NC6H4S) CR1] where R=CH3, R'=CH3,C6H5 and 4-CH3C6H4; R=CF3, R-1=CF3 and -C=CH-CH=CHS have been prepared by the reactions of triphenylantimony(III) and the corresponding ligands. These compounds have been characterised by elemental analyses, molecular weight determinations, IR,H-1, C-13 and F-19 NMR spectral studies.

  DOI：

  10.1081/sim-100002228

文献信息

• SYNTHESIS AND CHARACTERIZATION OF NEW RUTHENIUM(III) COMPLEXES CONTAINING TETRADENTATE SCHIFF BASES
  作者：T. Daniel Thangadurai、K. Natarajan

  DOI：10.1081/sim-100104786

  日期：2001.4.30

  Several new hexa-coordinated ruthenium(Ill) complexes of the type [RuX(EPh3)(LL')] (X = Cl, Br; E = P, As; LL' = anthacac, anthdibm, 2-amtpacac or 2-amtpdibm) have been synthesised by reacting [RUCl3(PPh3)(3)], [RUCl3(AsPh3)(3)], [RuBr3(AsPh3)(3)] or [RuBr3(PPh3)(2)(MeOH)] with tetradentate Schiff bases such as bis(anthranilic acid)acetylacetimine (H-2-anthacac), bis(anthranilic acid)dibenzoylmethimine (H-2-anthdibm), bis(2-aminothiophenol)acetylacetimine (H-2-2-amptacac) or bis(2-aminothiophenol)dibenzoylmethimine (H-2-2-amtpdibm). All of the complexes have been characterised by elemental analyses, IR, electronic spectra, EPR, magnetic moment and cyclic voltammetric data. An octahedral structure has been tentatively proposed for the complexes. These complexes were also tested for their antibacterial properties.