[Pd(N,N'-di(p-isopropylphenyl)-2-iminoisoindoline)(acetate)(triphenylphosphine)] | 1158090-15-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Pd(N,N'-di(p-isopropylphenyl)-2-iminoisoindoline)(acetate)(triphenylphosphine)]
• CAS: 1158090-15-3
• 化学式: C₄₆H₄₅N₂O₂PPd
• 分子量: 795.269
• InChiKey: YCXKUJMPPBPRHT-DTBIJOOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  bis(μ-acetato)(1-p-diisopropylphenylimino-2-p-diisopropylphenylisoindoline)dipalladium(II) 、 三苯基膦 以 丙酮 为溶剂， 以60%的产率得到[Pd(N,N'-di(p-isopropylphenyl)-2-iminoisoindoline)(acetate)(triphenylphosphine)]
  参考文献：
  名称：

  Mononuclear palladacycles of N,N′-diaryl-2-iminoisoindolines

  摘要：

  Reaction of acetato-bridged dinuclear palladacycles, [Pd(iminoisoindoline)(mu-OAc)](2), with stoichiometric amounts of PR3 (where R = Ph or Cy) resulted in formation of the corresponding mononuclear phosphine-ligated, six-membered palladacycles with the general formula [Pd(iminoisoindoline)(OAc) PR3]. The analogous chloride complexes were synthesized by reaction of [Pd(iminoisoindoline)(mu-OAc)](2) with LiCl in acetone followed by addition of phosphine to afford the monomeric derivatives [Pd(iminoisoindoline)(Cl)PR3]. Representative crystal structures of both types of mononuclear palladacycles confirmed the mononuclear nature of the complexes and showed a trans-arrangement of the phosphine ligand to the heterocyclic imine-nitrogen of the palladacycles. (c) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.12.055