thiocyanic acid ; tin (IV)-thiocyanate | 3602-20-8

• 分子结构分类: 有机化合物 - 有机硫化合物
• 英文名称: thiocyanic acid ; tin (IV)-thiocyanate
• 英文别名: Thiocyansaeure; Zinn(IV)-thiocyanat；Zinnthiocyanat
• CAS: 3602-20-8；23665-02-3；38847-93-7
• 化学式: 4CNS*Sn
• 分子量: 351.045
• InChiKey: VJAMPDSRWPZCTG-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.37
• 重原子数：
  4.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  23.79
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  thiocyanic acid ; tin (IV)-thiocyanate 、 [Fe-(N,N’-bis(2-hydroxybenzyliden)-1,6-diamino-3-azahexane(-2H))Cl] 在 triethylamine 作用下， 生成 [(Fe(N,N'-bis(2-hydroxybenzylidene)-1,6-diamino-3-azahexane(2-))NCS)4Sn]Cl4
  参考文献：
  名称：

  Molecular switching complexes with iron and tin as central atom

  摘要：

  The precursor [Fe-III(L)Cl] (LH2 = N,N'-bis(2'-hydroxy-benzyliden)-1,6-diamino-3-N-hexane is a high-spin (S = 5/2) complex. This precursor is combined with the bridging units [Sn-IV(X)(4)] (X = CN-, NCS-) to yield star-shaped pentanuclear clusters, [(LFeIII-X)(4)Sn]Cl-4. For X = CN- the Fe-57-Mossbauer data show a multiple spin transition between iron(III) in the high-spin and low-spin state, while the Sn-119m-Mossbauer data indicate a valence tautomerism between Sn(IV) and Sn(II). Changing the bridging unit from X = CN- to X = NCS- turns the switchability off. (C) 2009 Published by Elsevier Ltd.

  DOI：

  10.1016/j.poly.2008.12.028
• 作为产物：
  描述：

  potassium thioacyanate 、 四氯化锡 以 丙酮 为溶剂， 生成 thiocyanic acid ; tin (IV)-thiocyanate
  参考文献：
  名称：

  Molecular switching complexes with iron and tin as central atom

  摘要：

  The precursor [Fe-III(L)Cl] (LH2 = N,N'-bis(2'-hydroxy-benzyliden)-1,6-diamino-3-N-hexane is a high-spin (S = 5/2) complex. This precursor is combined with the bridging units [Sn-IV(X)(4)] (X = CN-, NCS-) to yield star-shaped pentanuclear clusters, [(LFeIII-X)(4)Sn]Cl-4. For X = CN- the Fe-57-Mossbauer data show a multiple spin transition between iron(III) in the high-spin and low-spin state, while the Sn-119m-Mossbauer data indicate a valence tautomerism between Sn(IV) and Sn(II). Changing the bridging unit from X = CN- to X = NCS- turns the switchability off. (C) 2009 Published by Elsevier Ltd.

  DOI：

  10.1016/j.poly.2008.12.028

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sn: MVol.C3, 28.16.2, page 168 - 168
  作者：

  DOI：——

  日期：——
• Brokaar, G.; Groeneveld, W. L.; Reedijk, J., Recueil des Travaux Chimiques des Pays-Bas, 1970, vol. 89, p. 1117 - 1120
  作者：Brokaar, G.、Groeneveld, W. L.、Reedijk, J.

  DOI：——

  日期：——