6,6'-((n-butyl)methylene)bis(2,4-dimethylphenol) | 133992-15-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 6,6'-((n-butyl)methylene)bis(2,4-dimethylphenol)
• 英文别名: 2,2'-(Pentane-1,1-diyl)bis(4,6-dimethylphenol)；2-[1-(2-hydroxy-3,5-dimethylphenyl)pentyl]-4,6-dimethylphenol
• CAS: 133992-15-1
• 化学式: C₂₁H₂₈O₂
• 分子量: 312.452
• InChiKey: MTGQWDUQHDWOHJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  23
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  正戊醛 、 2,4-二甲基苯酚 在 sulfonated reduced graphene oxide nanosheets 作用下， 以 水 为溶剂， 反应 0.13h， 以88%的产率得到6,6'-((n-butyl)methylene)bis(2,4-dimethylphenol)
  参考文献：
  名称：

  微波辅助还原水中多磺化还原氧化石墨烯纳米片催化合成6,6'-（芳基（烷基）亚甲基）双（2,4-二烷基苯酚）抗氧化剂

  摘要：

  使用场发射扫描电子显微镜（FESEM），透射电子显微镜（TEM），原子力显微镜（AFM），傅里叶变换红外光谱（FT-IR），拉曼光谱对磺化还原氧化石墨烯纳米片（RGO-SO 3 H）进行了表征，X射线衍射（XRD），热重分析（TGA）和酸碱滴定法。发现在还原的氧化石墨烯纳米片上负载的Multi-SO 3 H是一种有效的催化剂，用于由2,4-二烷基酚绿色合成6,6'-（芳基（烷基）亚甲基）双（2,4-二烷基苯酚）衍生物微波辐射下水性介质中的芳香族和脂肪族醛。在催化量的RGO-SO存在下进行6,6'-（芳基（烷基）亚甲基）双（2,4-二烷基苯酚）衍生物的合成在热和微波条件下3 H，分别以高产率和优异产率提供所需产物。另外，该催化剂可以容易地回收并重复使用几次，而其催化活性没有任何明显的损失。

  DOI：

  10.1039/c4nj02340d

文献信息

• CONDUCTIVE COMPOSITION, CONDUCTIVE MEMBER AND PRODUCTION METHOD THEREOF, TOUCH PANEL, AND SOLAR CELL
  申请人：FUJIFILM Corporation

  公开号：US20140202531A1

  公开（公告）日：2014-07-24

  A conductive composition includes at least: a) metal conductive fibers having an average minor axis length of from 1 nm to 150 nm; and b) a compound represented by the following Formula (1) or Formula (2) in an amount of from 0.1% by mass to 1000% by mass with respect to the metal conductive fibers: P—(CR 1 ═Y) n -Q  Formula (1) wherein, in Formula (1), P and Q each independently represent a group represented by OH, NR 2 R 3 or CHR 4 R 5 , in which R 2 and R 3 each independently represent a hydrogen atom or a group that can be substituted on a nitrogen atom, and R 4 and R 5 each independently represent a hydrogen atom or a substituent; Y represents CR 6 or a nitrogen atom; R 1 and R 6 each independently represent a hydrogen atom or a substituent; at least two of the groups represented by R 1 , R 2 , R 3 , R 4 , R 5 or R 6 may be bonded to each other to form a ring; n represents an integer from 0 to 5; when n is 0, neither P nor Q is a group represented by OH or CHR 4 R 5 ; and when n represents a number of 2 or greater, the plurality of atomic groups each represented by (CR 1 ═Y) may be the same as or different from each other; R 7 —C(═O)—H  Formula (2) wherein, in Formula (2), R 7 represents a hydrogen atom, an OH group, an alkyl group, an alkenyl group, an alkynyl group, an aryl group or a heterocyclic group.
• ORGANIC SEMICONDUCTOR COMOSITION, ORGANIC THIN-FILM TRANSISTOR, ELECTRONIC PAPER, AND DISPLAY DEVICE
  申请人：FUJIFILM Corporation

  公开号：US20160064674A1

  公开（公告）日：2016-03-03

  An object of the present invention is to provide an organic semiconductor composition, which improves the insulation reliability of an organic thin-film transistor without greatly reducing the mobility of the organic thin-film transistor, an organic thin-film transistor which is prepared by using the organic semiconductor composition, and electronic paper and a display device which use the organic thin-film transistor. The organic semiconductor composition of the present invention contains an organic semiconductor material (A) and a polymer compound (B) containing a repeating unit represented by the following Formula (B).
• US7951310B2
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  公开号：US7951310B2

  公开（公告）日：2011-05-31
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