4'-propyl-3,5-difluoro-4-iodobiphenyl | 147437-98-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4'-propyl-3,5-difluoro-4-iodobiphenyl
• 英文别名: 3,5-difluoro-4-iodo-4'-propylbiphenyl；1,3-difluoro-2-iodo-5-(4-propylphenyl)benzene
• CAS: 147437-98-7
• 化学式: C₁₅H₁₃F₂I
• 分子量: 358.17
• InChiKey: LZQCNGISQBDXAT-UHFFFAOYSA-N

物化性质

• 沸点：
  359.0±42.0 °C(Predicted)
• 密度：
  1.527±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  3',5'-二氟-4-丙基联苯 在 碘 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 7.0h， 以77%的产率得到4'-propyl-3,5-difluoro-4-iodobiphenyl
  参考文献：
  名称：

  LIQUID CRYSTAL COMPOUND, LIQUID CRYSTAL COMPOSITION AND LIQUID CRYSTAL DISPLAY ELEMENT

  摘要：

  公开号：

  EP2522649B1

文献信息

• Liquid crystal composition comprising novel silicon containing compounds and liquid crystal display device using the same
  申请人：Cheong Ho Jae

  公开号：US20060151744A1

  公开（公告）日：2006-07-13

  Disclosed are a silicon-containing compound, a liquid crystal composition comprising the same compound, and a liquid crystal display device comprising a liquid crystal layer prepared from the liquid crystal composition. The silicon-containing compound, which forms the liquid crystal composition, has low viscosity and high positive dielectric anisotropy. Therefore, it is possible to provide a liquid crystal display device, which has a fast response time and can be driven at a low voltage.

  本发明涉及一种含硅化合物、包含该化合物的液晶组合物以及由该液晶组合物制备的液晶显示器件。所述含硅化合物形成液晶组合物，具有低粘度和高正电介质各向异性。因此，可以提供一种具有快速响应时间且可以在低电压下驱动的液晶显示器件。
• LIQUID CRYSTAL COMPOUND, LIQUID CRYSTAL COMPOSITION AND LIQUID CRYSTAL DISPLAY DEVICE
  申请人：Tanaka Hiroyuki

  公开号：US20130119310A1

  公开（公告）日：2013-05-16

  To provide a novel liquid crystal compound having general physical properties necessary for the compound, namely, stability to heat, light and so forth, a wide temperature range of a liquid crystal phase, a high clearing point, a good compatibility with other compounds, a large refractive index anisotropy, a large dielectric anisotropy and a small viscosity. The liquid crystal compound is provided as compound (1): wherein, for example, R 1 is alkyl having 1 to 20 carbons; ring A 1 and ring B 1 are 1,4-cyclohexylene or 1,4-phenylene; Z 1 and Z 2 are a single bond, —CH 2 CH 2 —, —CH═CH— or —C≡C—; L 1 is fluorine; L 2 , Y 1 and Y 2 are hydrogen, fluorine or chlorine; and X 1 is halogen, —C≡N or alkyl having 1 to 10 carbons, and in the alkyl, arbitrary —CH 2 — may be replaced by —O— or —S—, and m is 1 and n is 0.

  为提供一种具有一般化合物所需的物理特性的新型液晶化合物，即耐热、耐光等稳定性、广泛的液晶相温度范围、高清除点、与其他化合物良好的相容性、大的折射率各向异性、大的介电各向异性和小的粘度。该液晶化合物提供为化合物（1）：其中，例如，R1为具有1至20个碳的烷基；环A1和环B1为1,4-环己基或1,4-苯基；Z1和Z2为单键，- -，-CH═CH-或-C≡C-；L1为氟；L2、Y1和Y2为氢、氟或氯；X1为卤素，-C≡N或具有1至10个碳的烷基，在烷基中，任意-CH2-可以被-O-或-S-所替代，m为1，n为0。
• Liquid crystal compound, liquid crystal composition and liquid crystal display device
  申请人：Tanaka Hiroyuki

  公开号：US08940185B2

  公开（公告）日：2015-01-27

  To provide a novel liquid crystal compound having general physical properties necessary for the compound, namely, stability to heat, light and so forth, a wide temperature range of a liquid crystal phase, a high clearing point, a good compatibility with other compounds, a large refractive index anisotropy, a large dielectric anisotropy and a small viscosity. The liquid crystal compound is provided as compound (1): wherein, for example, R1 is alkyl having 1 to 20 carbons; ring A1 and ring B1 are 1,4-cyclohexylene or 1,4-phenylene; Z1 and Z2 are a single bond, —CH2CH2—, —CH═CH— or —C≡C—; L1 is fluorine; L2, Y1 and Y2 are hydrogen, fluorine or chlorine; and X1 is halogen, —C≡N or alkyl having 1 to 10 carbons, and in the alkyl, arbitrary —CH2— may be replaced by —O— or —S—, and m is 1 and n is 0.

  为提供一种新型液晶化合物，具有化合物所需的一般物理特性，即热稳定性、光稳定性等，液晶相的宽温度范围、高清晰点、与其他化合物良好的相容性、大折射率各向异性、大介电各向异性和小粘度。所提供的液晶化合物为化合物（1）：其中，例如，R1是具有1至20个碳原子的烷基；环A1和环B1是1,4-环己基或1,4-苯基；Z1和Z2是单键，- -，-CH═CH-或-C≡C-；L1是氟；L2、Y1和Y2是氢、氟或氯；X1是卤素，-C≡N或具有1至10个碳原子的烷基，在烷基中，任意-CH2-可以被- O-或-S-所替代，m为1，n为0。
• Terphenyl derivative, liquid crystal composition and liquid crystal display device
  申请人：CHISSO CORPORATION

  公开号：US20010038092A1

  公开（公告）日：2001-11-08

  The present invention provides liquid crystalline compounds having a high voltage holding ratio and a low threshold voltage, little variation of these properties with temperature change, high &Dgr;n, and good compatibility with other liquid crystal materials particularly under a low temperature; liquid crystal compositions containing these crystalline compounds; and liquid crystal display devices made using these liquid crystal compositions. The liquid crystalline compounds are terphenyl derivatives represented by general formula (1): 1 wherein R represents a straight or branched alkyl group of 1-20 carbon atoms, and any methylene groups (—CH 2 —) not adjacent each other in each alkyl group may be replaced by oxygen atoms; X is a halogen atom, —OCF 3 , —OCF 2 H, —CF 3 , —CF 2 H or —CFH 2 ; Y 1 , Y 2 , Y 3 , Y 4 , Y 5 and Y 6 independently represents H or F, but at least two of Y 1 , Y 2 , Y 3 and Y 4 represent F; and any atom constituting these compounds may be substituted by its isotope.

  本发明提供了具有高电压保持比和低阈值电压、这些性质随温度变化的变化很小、高&Dgr;n以及与其他液晶材料在低温下具有良好兼容性的液晶化合物；包含这些晶体化合物的液晶组合物；以及使用这些液晶组合物制成的液晶显示装置。这些液晶化合物是由通式（1）表示的三苯基衍生物：1其中R表示1-20个碳原子的直链或支链烷基，每个烷基中不相邻的任何亚甲基（—CH2—）可以被氧原子替换；X是卤素原子、—O 、—OCF2H、—CF3、—CF2H或—CFH2；Y1、Y2、Y3、Y4、Y5和Y6独立地表示H或F，但其中至少有两个Y1、Y2、Y3和Y4表示F；这些化合物构成的任何原子都可以被其同位素替换。
• TERPHENYL DERIVATIVE, LIQUID-CRYSTAL COMPOSITION, AND LIQUID-CRYSTAL DISPLAY ELEMENT
  申请人：CHISSO CORPORATION

  公开号：EP0989107A1

  公开（公告）日：2000-03-29

  The present invention provides liquid crystalline compounds having a high voltage holding ratio and a low threshold voltage, little variation of these properties depending on temperature change, high Δn, and good compatibility with other liquid crystal materials particularly under a low temperature; liquid crystal compositions containing these crystalline compounds; and liquid crystal display devices constituted by using these liquid crystal compositions. The liquid crystalline compounds are terphenyl derivatives represented by general formula (1): wherein R represents a straight or branched alkyl group of 1-20 carbon atoms, and any methylene groups (-CH2-) not adjacent each other in each alkyl group may be replaced by oxygen atoms; X shows an halogen atom, -OCF3, -OCF2H, -CF3, -CF2H or -CFH2; Y1, Y2, Y3, Y4, Y5 and Y6 independently represents H or F, but at least two of Y1, Y2, Y3 and Y4 represent F; and any atom constituting these compounds may be substituted by its isotope.

  本发明提供了具有高电压保持率和低阈值电压、这些特性随温度变化而变化小、高Δn 和与其他液晶材料良好兼容性（特别是在低温条件下）的液晶化合物；含有这些液晶化合物的液晶组合物；以及使用这些液晶组合物构成的液晶显示设备。液晶化合物是由通式（1）表示的三联苯衍生物： 其中 R 代表 1-20 个碳原子的直链或支链烷基，每个烷基中不相邻的亚甲基（-CH2-）可由氧原子取代；X表示卤素原子、-O 、-OCF2H、-CF3、-CF2H或-CFH2；Y1、Y2、Y3、Y4、Y5和Y6各自代表H或F，但Y1、Y2、Y3和Y4中至少有两个代表F；构成这些化合物的任何原子都可以被其同位素取代。