Benzoic acid N'-allyl-N'-methyl-hydrazide | 33250-27-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Benzoic acid N'-allyl-N'-methyl-hydrazide
• CAS: 33250-27-0
• 化学式: C₁₁H₁₄N₂O
• 分子量: 190.245
• InChiKey: ASGJPKOZSHPWHZ-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  Benzoic acid N'-allyl-N'-methyl-hydrazide 在 亚硝酸特丁酯 、 氧气 作用下， 以 氯仿 为溶剂， 以22%的产率得到N-allyl-N′-benzoylnitrous hydrazide
  参考文献：
  名称：

  C–N Bond Activation of N,N′-Dialkylacylhydrazines Mediated by β-Fragmentation of Nitrogen-Centered Radical

  摘要：

  In the presence of tert-butylnitrite and dioxygen, the C-N bond activation of N,N'-dialkylacylhydrazines was realized, providing a series of N-nitrosoacylhydrazines in high yields. Different from transition-metal and other radical catalysis, this reaction is mediated by a nitrogen-centered radical of the corresponding N,N'-dialkylacylhydrazine and further beta-fragmentation, which was supported by the mechanistic study.

  DOI：

  10.1021/acs.joc.9b01851