hydrido[2-[(imino-κN)phenylmethyl]-2-methylphenyl-κC]tris(trimethylphosphine)iron(II) | 1140507-59-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: hydrido[2-[(imino-κN)phenylmethyl]-2-methylphenyl-κC]tris(trimethylphosphine)iron(II)
• CAS: 1140507-59-0
• 化学式: C₂₃H₄₀FeNP₃
• 分子量: 479.346
• InChiKey: QAZFUIQSWIAAEJ-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  hydrido[2-[(imino-κN)phenylmethyl]-2-methylphenyl-κC]tris(trimethylphosphine)iron(II) 、 碘甲烷 以 正戊烷 为溶剂， 以72%的产率得到iodo[2-[(imino-κN)phenylmethyl]-2-methylphenyl-κC]tris(trimethylphosphine)iron(II)
  参考文献：
  名称：

  C−H Activation of Imines by Trimethylphosphine-Supported Iron Complexes and Their Reactivities

  摘要：

  First examples of ortho-metalated mono-iron complexes of monodentate N-donor ligands via C-H activation have been synthesized. Treatment of benzylicimines and ketimines with Fe(CH3)(2)(PMe3)(4) and Fe(PMe3)(4) under mild conditions results in ortho-metalated hydrido-iron(II) and methyl-iron(II) complexes in high yields, and their iodomethane reactions give thermally stable iodo-iron(II) compounds, which are interesting versatile nucleophiles in organometallic and organic chemistry.

  DOI：

  10.1021/om800828j
• 作为产物：
  描述：

  二苯甲酮亚胺 、 dimethyltetrakis(trimethylphosphane)iron(II) 以 正戊烷 为溶剂， 以74%的产率得到hydrido[2-[(imino-κN)phenylmethyl]-2-methylphenyl-κC]tris(trimethylphosphine)iron(II)
  参考文献：
  名称：

  C−H Activation of Imines by Trimethylphosphine-Supported Iron Complexes and Their Reactivities

  摘要：

  First examples of ortho-metalated mono-iron complexes of monodentate N-donor ligands via C-H activation have been synthesized. Treatment of benzylicimines and ketimines with Fe(CH3)(2)(PMe3)(4) and Fe(PMe3)(4) under mild conditions results in ortho-metalated hydrido-iron(II) and methyl-iron(II) complexes in high yields, and their iodomethane reactions give thermally stable iodo-iron(II) compounds, which are interesting versatile nucleophiles in organometallic and organic chemistry.

  DOI：

  10.1021/om800828j