| 905595-26-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• CAS: 905595-26-8
• 化学式: C₂₃H₁₉N₃OPd
• 分子量: 459.843
• InChiKey: YFZWTTRMEXLHEJ-BUFQOAPZSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  4-甲基吡啶 、 sodium tetrachloropalladate(II) 、 1-<3-Methyl-6-hydroxy-phenylazo>-naphthalin 以 乙醇 、 苯 为溶剂， 以47.5%的产率得到
  参考文献：
  名称：

  Regiospecific cyclometallation: Synthesis, spectral properties and crystal structure of peri-palladate

  摘要：

  At room temperature 1-(2'-hydroxy-5'-methylphenylazo)naphthalene (H2L) reacts with disodium tetrachloropalladate in ethanol and undergoes cyclopalladation leading to the formation of the pink monomeric compound [PdL(Pic)] (1) in the presence of 4-picoline (Pic). The structure of I has been determined by single crystal X-ray crystallography. The metal ion is in a distorted square planar CNON coordination sphere. The palladium(II)-carbon bond formation occurs exclusively at the C8 (peri-) position of the naphthyl ring of H2L. 1-(2'-hydroxy-5'-methylphenylazo)naphthalene behaves as a dianionic terdentate [U(naphthyl), N(diazo). O(phenotato)] ligand towards palladium(II). The peri-palladate 1 has also been characterized by spectral (IR, electronic. H-1 and Cf-13{H-1} NMR) data. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.12.029