dichloropalladium;1-methyl-4-nitrosobenzene | 95246-30-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: dichloropalladium;1-methyl-4-nitrosobenzene
• CAS: 95246-30-3
• 化学式: C₁₄H₁₄Cl₂N₂O₂Pd
• 分子量: 419.603
• InChiKey: TXYLJSCWSZODOX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二(氰基苯)二氯化钯 、 对硝基甲苯 以 二氯甲烷 为溶剂， 生成 dichloropalladium;1-methyl-4-nitrosobenzene
  参考文献：
  名称：

  Coordination complexes of palladium dichloride with 4-substituted nitrosobenzenes

  摘要：

  Complexes of 4-substituted nitrosobenzenes with palladium dichloride have been prepared and studied by solid state CP/MAS C-13 NMR spectroscopy. The results obtained are discussed in terms of the unique property of the nitroso group based upon its high pi-electron accepting character. It is shown that this property is maintained when the NO group undergoes sigma(N) coordination to palladium in contrast to recent evidence that pi(NO) coordination to molybenum removes this property. The effect of coordination upon the chemical shifts of the other ring carbons is also discussed.

  DOI：

  10.1016/0277-5387(95)00024-m