zinc 2(3),9(10),16(17),23(24)-tetra(3-pyridinemethoxy)phthalocyaninate | 1501972-37-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: zinc 2(3),9(10),16(17),23(24)-tetra(3-pyridinemethoxy)phthalocyaninate
• CAS: 1501972-37-7
• 化学式: C₅₆H₃₆N₁₂O₄Zn
• 分子量: 1006.37
• InChiKey: PEMALKDDTKFIAJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  zinc 2(3),9(10),16(17),23(24)-tetra(3-pyridinemethoxy)phthalocyaninate 、 2-氯乙醇 反应 2.0h， 以64%的产率得到zinc 2(3),9(10),16(17),23(24)-tetra[3-(N-2-oxyethyl)pyridinemethoxy]phthalocyaninate chloride
  参考文献：
  名称：

  Synthesis and spectral characteristics of water-soluble pyridine-containing phthalocyanines of cation type

  摘要：

  Soluble in aqueous acids phthalocyanine ligands and metallophthalocyanines, containing the peripheral pyridine fragments were synthesized from the corresponding phthalodinitriles. The quaternization of the pyridine-containing phthalocyanines using 2-chloroethanol afforded water-soluble phthalocyanine ligands and metal complexes. The new compounds were characterized by NMR, EAS, and MALDI-TOF mass spectrometry.

  DOI：

  10.1134/s1070363213100198
• 作为产物：
  描述：

  zinc(II) acetate dihydrate 、 4-(pyridin-3-ylmethoxy)phthalonitrile 在 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 正己醇 为溶剂， 反应 8.0h， 以68%的产率得到zinc 2(3),9(10),16(17),23(24)-tetra(3-pyridinemethoxy)phthalocyaninate
  参考文献：
  名称：

  Synthesis and spectral characteristics of water-soluble pyridine-containing phthalocyanines of cation type

  摘要：

  Soluble in aqueous acids phthalocyanine ligands and metallophthalocyanines, containing the peripheral pyridine fragments were synthesized from the corresponding phthalodinitriles. The quaternization of the pyridine-containing phthalocyanines using 2-chloroethanol afforded water-soluble phthalocyanine ligands and metal complexes. The new compounds were characterized by NMR, EAS, and MALDI-TOF mass spectrometry.

  DOI：

  10.1134/s1070363213100198