syn-(5,15-bis[3'-(diphenylphosphinyl)biphenyl-2-yl]porphyrinato)zinc(II) | 756499-10-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: syn-(5,15-bis[3'-(diphenylphosphinyl)biphenyl-2-yl]porphyrinato)zinc(II)
• CAS: 756499-10-2
• 化学式: C₆₈H₄₆N₄P₂Zn
• 分子量: 1046.48
• InChiKey: MKXPGLFMHMTCKE-YVHGIVHXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  二氯甲烷 、 syn-(5,15-bis[3'-(diphenylphosphinyl)biphenyl-2-yl]porphyrinato)zinc(II) 、 di(rhodium)tetracarbonyl dichloride 以 四氢呋喃 为溶剂， 以20%的产率得到
  参考文献：
  名称：

  Synthesis of Dinuclear Complexes Bearing Metalloporphyrin−Phosphine Hybrid Ligands and Their Catalytic Activity toward Hydrosilylation of Ketones

  摘要：

  A new type of metalloporphyrin-phosphine hybrid ligand (1) has been designed and synthesized. Reactions of some transition metal complexes such as PdCl2, PtCl2, and [RhCl(CO)(2)](2) with a zinc porphyrin-phosphine ligand (1; M-1 = Zn) afford the corresponding dinuclear complexes (2) bearing the hybrid ligand. The zinc porphyrin-phosphine compound (1; M-1 = Zn, R = Ph) has been found to work as an effective ligand for Rh(I)- or Ir(I)-catalyzed hydrosilylation of ketones to give the corresponding alcohols after acid hydrolysis.

  DOI：

  10.1021/om0498201
• 作为产物：
  描述：

  syn-(5,15-bis[3'-(diphenylphosphinothioyl)biphenyl-2-yl]porphyrinato)zinc(II) * 2CH2Cl2 在 chlorohydridobis(cyclopentadienyl)zirconium 作用下， 以 四氢呋喃 为溶剂， 以81%的产率得到syn-(5,15-bis[3'-(diphenylphosphinyl)biphenyl-2-yl]porphyrinato)zinc(II)
  参考文献：
  名称：

  Synthesis of Dinuclear Complexes Bearing Metalloporphyrin−Phosphine Hybrid Ligands and Their Catalytic Activity toward Hydrosilylation of Ketones

  摘要：

  A new type of metalloporphyrin-phosphine hybrid ligand (1) has been designed and synthesized. Reactions of some transition metal complexes such as PdCl2, PtCl2, and [RhCl(CO)(2)](2) with a zinc porphyrin-phosphine ligand (1; M-1 = Zn) afford the corresponding dinuclear complexes (2) bearing the hybrid ligand. The zinc porphyrin-phosphine compound (1; M-1 = Zn, R = Ph) has been found to work as an effective ligand for Rh(I)- or Ir(I)-catalyzed hydrosilylation of ketones to give the corresponding alcohols after acid hydrolysis.

  DOI：

  10.1021/om0498201