[C(E)]-4-methoxybenzaldehyde 2-([2,2':6',2''-terpyridin]-4'-yl)hydrazone | 1202815-84-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [C(E)]-4-methoxybenzaldehyde 2-([2,2':6',2''-terpyridin]-4'-yl)hydrazone
• CAS: 1202815-84-6
• 化学式: C₂₃H₁₉N₅O
• 分子量: 381.437
• InChiKey: FMISMSIXLGTSKM-WGOQTCKBSA-N

反应信息

• 作为产物：
  描述：

  在 potassium hydrogencarbonate 作用下， 以 二氯甲烷 、 水 为溶剂， 反应 1.0h， 以74%的产率得到[C(E)]-4-methoxybenzaldehyde 2-([2,2':6',2''-terpyridin]-4'-yl)hydrazone
  参考文献：
  名称：

  Building Functionality into 4′-Hydrazone Derivatives of 2,2′: 6′,2″-Terpyridine

  摘要：

  AbstractThe syntheses of the five 2,2′: 6′,2″‐terpyridine (tpy) ligands 5–9 functionalized in the 4′‐position with a hydrazone substituent RR′CNNH (R=R′=Me; R=H, R′=4‐BrC6H4, 4‐O2NC6H4, 4‐MeOC6H4, or 3,5‐(MeO)2C6H3) are described. Protonation of the tpy domain of the ligands is facile. Solution behaviour has been studied by NMR and electronic spectroscopies. Representative structural data are presented for neutral and monoprotonated ligands, and illustrate that H‐bonding involving the formal amine NH unit is a dominant structural motif in all cases.

  DOI：

  10.1002/hlca.200900132