Dichloromethane;[dichloro-[(trichloro-lambda5-phosphanylidene)amino]-lambda5-phosphanylidene]-(trichloro-lambda5-phosphanylidene)azanium;chloride | 697303-07-4

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦及其衍生物
• 英文名称: Dichloromethane;[dichloro-[(trichloro-lambda5-phosphanylidene)amino]-lambda5-phosphanylidene]-(trichloro-lambda5-phosphanylidene)azanium;chloride
• 英文别名: dichloromethane;[dichloro-[(trichloro-λ5-phosphanylidene)amino]-λ5-phosphanylidene]-(trichloro-λ5-phosphanylidene)azanium;chloride
• CAS: 697303-07-4
• 化学式: CH₂Cl₂*Cl*Cl₈N₂P₃
• 分子量: 524.945
• InChiKey: BUDHFYGDRKDZFE-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  6.23
• 重原子数：
  17
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  13.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  Dichloromethane;[dichloro-[(trichloro-lambda5-phosphanylidene)amino]-lambda5-phosphanylidene]-(trichloro-lambda5-phosphanylidene)azanium;chloride 、 二(三甲基硅基)碳酰二亚胺 以 二氯甲烷 为溶剂， 生成 (7E)-2,2,4,4,6,6,8-heptachloro-1,3,5,7-tetraza-2λ5,4λ5,6λ5-triphosphacycloocta-1,3,5,7-tetraene 、 (7Z,15Z)-2,2,4,4,6,6,8,10,10,12,12,14,14,16-tetradecachloro-1,3,5,7,9,11,13,15-octaza-2lambda5,4lambda5,6lambda5,10lambda5,12lambda5,14lambda5-hexaphosphacyclohexadeca-1,3,5,7,9,11,13,15-octaene
  参考文献：
  名称：

  A New, Convenient Synthesis of the Linear Phosphazene Salt [Cl₃PNPCl₃]Cl:  Preparation of Higher Linear Homologues [Cl₃PN−(PCl₂N)_xPCl₃]Cl (x = 1−3) and the 16-Membered Macrocycle [NCCl(NPCl₂)₃]₂

  摘要：

  An improved synthetic route to the linear phosphazene salt [CI3-P=N=PCI3]CI is reported. This species is a useful precursor to higher linear homologues and also to heterocycles such as the 16-membered carbophosphazene macrocycle [NCCI(NPCI2)(3)](2.)

  DOI：

  10.1021/ic049955z
• 作为产物：
  描述：

  二氯甲烷 、 trichloro(trimethylsilyl)phosphoranimine 、 bis(trichlorophosphine)iminium chloride 以 二氯甲烷 为溶剂， 以59%的产率得到Dichloromethane;[dichloro-[(trichloro-lambda5-phosphanylidene)amino]-lambda5-phosphanylidene]-(trichloro-lambda5-phosphanylidene)azanium;chloride
  参考文献：
  名称：

  A New, Convenient Synthesis of the Linear Phosphazene Salt [Cl₃PNPCl₃]Cl:  Preparation of Higher Linear Homologues [Cl₃PN−(PCl₂N)_xPCl₃]Cl (x = 1−3) and the 16-Membered Macrocycle [NCCl(NPCl₂)₃]₂

  摘要：

  An improved synthetic route to the linear phosphazene salt [CI3-P=N=PCI3]CI is reported. This species is a useful precursor to higher linear homologues and also to heterocycles such as the 16-membered carbophosphazene macrocycle [NCCI(NPCI2)(3)](2.)

  DOI：

  10.1021/ic049955z