2,4,6-trimethyl-N,N'-bis-(pyridin-2-ylmethylene)benzene-1,3-diamine | 1354921-91-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 2,4,6-trimethyl-N,N'-bis-(pyridin-2-ylmethylene)benzene-1,3-diamine
• CAS: 1354921-91-7
• 化学式: C₂₁H₂₀N₄
• 分子量: 328.417
• InChiKey: PHTHMGRJLNGDSC-GUJRAXHGSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  25.0
• 可旋转键数：
  4.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  50.5
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  2,4,6-trimethyl-N,N'-bis-(pyridin-2-ylmethylene)benzene-1,3-diamine 以 乙腈 为溶剂， 反应 0.17h， 生成 2,4,6-trimethyl-N,N'-bis-(pyridin-2-ylmethylene)benzene-1,3-diamine
  参考文献：
  名称：

  Photoassisted “Gate-Lock” Fluorescence “Turn-on” in a New Schiff Base and Coordination Ability of E–Z Isomers

  摘要：

  Rapid photoresponse (1.0-8.0 min) through fluorescence "turn-on" signaling displayed by a novel Schiff base (L) creating "gate lock" via intramolecular C-H center dot center dot center dot N interaction in photoisomerized product (L') has been described. Coordination chemistry of pre- and postirradiated species demonstrated a drastic change in the reactivity which has been supported by NMR, HRMS, UV-vis, emission, electrochemical, and complexation studies.

  DOI：

  10.1021/ol2032043
• 作为产物：
  描述：

  吡啶-2-甲醛 、 2,4,6-三甲基-1,3-苯二胺 以 苯 为溶剂， 反应 8.0h， 以83%的产率得到2,4,6-trimethyl-N,N'-bis-(pyridin-2-ylmethylene)benzene-1,3-diamine
  参考文献：
  名称：

  Photoassisted “Gate-Lock” Fluorescence “Turn-on” in a New Schiff Base and Coordination Ability of E–Z Isomers

  摘要：

  Rapid photoresponse (1.0-8.0 min) through fluorescence "turn-on" signaling displayed by a novel Schiff base (L) creating "gate lock" via intramolecular C-H center dot center dot center dot N interaction in photoisomerized product (L') has been described. Coordination chemistry of pre- and postirradiated species demonstrated a drastic change in the reactivity which has been supported by NMR, HRMS, UV-vis, emission, electrochemical, and complexation studies.

  DOI：

  10.1021/ol2032043