N-4-diethylaminosalicylidene-N'-4-(4-nitrophenylethylidene)-benzoyl-hydrazine | 482321-49-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-4-diethylaminosalicylidene-N'-4-(4-nitrophenylethylidene)-benzoyl-hydrazine
• CAS: 482321-49-3
• 化学式: C₂₆H₂₆N₄O₄
• 分子量: 458.517
• InChiKey: ZTHCAPOYKYFFCD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.08
• 重原子数：
  34.0
• 可旋转键数：
  9.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.15
• 拓扑面积：
  108.07
• 氢给体数：
  2.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  N-4-diethylaminosalicylidene-N'-4-(4-nitrophenylethylidene)-benzoyl-hydrazine 、 copper diacetate 在 sodium acetate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以60%的产率得到Cu2(N-4-diethylaminosalicylidene-N'-4-(4-nitrophenylethylidene)-benzoyl-hydrazine)2
  参考文献：
  名称：

  Synthesis, Structure, and Second-Order Nonlinear Optical Properties of Copper(II) and Palladium(II) Acentric Complexes with N-Salicylidene-N ‘-aroylhydrazine Tridentate Ligands

  摘要：

  Two new N-salicylidene-N'-aroylhydrazines ligands have been prepared: N-4-diethylaminosalicylidene-N'-4-nitrobenzoyl-hydrazine (L-1) and N-4-diethylaminosalicylidene-N'-4-(4-nitrophenylethylidene)-benzoyl-hydrazine (L-2). The ligands are properly functionalized with strong electron donor-acceptor groups and are of potential interest in second-order nonlinear optics (NLO), Dimeric copper(II) and palladium(II) complexes with L-1 and L-2 have been prepared, and, starting from these, mononuclear acentric adducts with pyridine as a further ligand have been prepared and characterized. The X-ray structures of three adducts are also reported. The NLO activity of the adducts has been determined by EFISH measurements giving mubeta values up to 1500 x 10(-48) esu for an incident wavelength of 1.907 mum.

  DOI：

  10.1021/ic020127k

文献信息

• Grafting Poly(4‐vinylpyridine) with a Second‐Order Nonlinear Optically Active Nickel( <scp>II</scp> ) Chromophore
  作者：Ugo Caruso、Roberto Centore、Barbara Panunzi、Antonio Roviello、Angela Tuzi

  DOI：10.1002/ejic.200400903

  日期：2005.7

  commercial poly(4-vinylpyridine) (average molecular weight 60000 or 160000) with a NiII chromophore complex. The metal-containing chromophore was obtained from a tridentate benzoylhydrazine ligand. Chromophore fragments were grafted onto the polymer by formation of a coordinative bond between the metal and the pyridinic nitrogen. Two acentric mononuclear NiII complexes containing pyridine as an additional

  含金属的聚合物是通过用 NiIII 发色团络合物接枝商业聚（4-乙烯基吡啶）（平均分子量 60000 或 160000）获得的。含金属的生色团是从三齿苯甲酰肼配体获得的。通过在金属和吡啶氮之间形成配位键，发色团片段接枝到聚合物上。已在方形平面或八面体环境中制备了两种含有吡啶作为附加配体的无心单核 NiIII 复合物，并通过单晶 X 射线分析对其进行了表征。检查模型复合物和接枝聚合物的化学和热性能，并将其与基于 CuII 和 PdII 的那些进行比较，特别是参考它们的 NLO 性能。(© Wiley-VCH Verlag GmbH & Co. KGaA,