1,3,5-tris(benzylsulfanyl)benzene | 528522-54-5

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 1,3,5-tris(benzylsulfanyl)benzene
• CAS: 528522-54-5
• 化学式: C₂₇H₂₄S₃
• 分子量: 444.686
• InChiKey: DAFMIWRJCJHYQV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.9
• 重原子数：
  30
• 可旋转键数：
  9
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  75.9
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1,3,5-tris(benzylsulfanyl)benzene 、 silver perchlorate 以 丙酮 为溶剂， 以45%的产率得到[Ag2(1,3,5-tris(benzylsulfanyl)benzene)2(ClO4)2]
  参考文献：
  名称：

  Crystal structure and photo-induced property of two-dimensional silver(I) complex with 1,3,5-tris(benzylsulfanyl)benzene

  摘要：

  The silver(l) complex [Ag-2(3bsb)(2)(ClO4)(2)] (1) (3bsb; 1,3,5-tris(benzylsulfanyl)benzene) has been prepared and its molecular structure was determined by X-ray crystallography. In 1, the silver ion prefers a tetrahedral coordination geometry and produces a two-dimensional sheet structure containing dimeric units. Irradiation of this complex 1 with light changes its color from white to pink; heat or exposure to acetone vapor makes the irradiated sample revert back to white. However, only 3bsb has no characteristic like this photochromism. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1387-7003(02)00780-3