3-(3-amino-phenoxy)-benzoic acid | 132930-52-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-(3-amino-phenoxy)-benzoic acid
• 英文别名: 3-(3-Amino-phenoxy)-benzoesaeure；3-(3-Aminophenoxy)benzoic acid
• CAS: 132930-52-0
• 化学式: C₁₃H₁₁NO₃
• 分子量: 229.235
• InChiKey: AVTOKKNRIIVCOS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  72.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  3-(3-nitro-phenoxy)-benzoic acid 在 一水合肼 作用下， 生成 3-(3-amino-phenoxy)-benzoic acid
  参考文献：
  名称：

  Ikawa, Yakugaku Zasshi/Journal of the Pharmaceutical Society of Japan, 1955, vol. 75, p. 457,459

  摘要：

  DOI：

文献信息

• PROCESS FOR PRODUCING POLYCONDENSATE FROM POLYCARBOXYLIC ACID AND POLYAMINE
  申请人：Japan Science and Technology Corporation

  公开号：EP1167422A1

  公开（公告）日：2002-01-02

  A process by which a polyamide, polyimide, or polyamide-imide capable of being easily purified after reaction, especially an aromatic polyamide (aramid), aromatic polyimide, or aromatic polyamide-imide, which is difficult to synthesize by direct polycondensation, is produced in high yield from a polycarboxylic acid and a polyamine by direct polycondensation with heating while inhibiting side reactions, e.g., one accompanied by a color change into black. An aromatic dicarboxylic acid, aromatic tetracarboxylic acid, or aromatic tricarboxylic acid is condensation-polymerized with an aromatic diamine using an arylboric acid, e.g., 3,4,5-trifluorophenylboric acid, as a polycondensation catalyst in the presence of either a mixed solvent comprising pentamethylbenzene and N-methylpyrrolidinone or a mixed solvent comprising m-terphenyl and N-butylpyrrolidinone to obtain a polyamide, polyimide, or polyamide-imide in high yield.

  一种在反应后易于提纯的聚酰胺、聚酰亚胺或聚酰胺-酰亚胺，特别是难以通过直接缩聚反应合成的芳香族聚酰胺（芳纶）、芳香族聚酰亚胺或芳香族聚酰胺-酰亚胺，通过加热直接缩聚反应，同时抑制副反应（如伴随颜色变黑的副反应），以高产率从聚羧酸和多胺制得的工艺。芳香族二羧酸、芳香族四羧酸或芳香族三羧酸与芳香族二胺使用芳基硼酸（如 3,4,5-三氟硼酸）进行缩合聚合、3,4,5-三氟苯硼酸作为缩聚催化剂，在由五甲基苯和 N-甲基吡咯烷酮组成的混合溶剂或由间三联苯和 N-丁基吡咯烷酮组成的混合溶剂存在下，与芳香族二胺进行缩合聚合，从而获得高产率的聚酰胺、聚酰亚胺或聚酰胺-酰亚胺。
• KOHLER, BURKHARD
  作者：KOHLER, BURKHARD

  DOI：——

  日期：——
• PROCESS OF PREPARING CONDENSED POLYMERS WITH POLYCARBOXYLIC ACIDS AND POLYAMINES
  申请人：Japan Science and Technology Agency

  公开号：EP1167422B1

  公开（公告）日：2005-06-01
• METHOD OF PREPARING NITROGEN-DOPED GRAPHENE AND NITROGEN-DOPED GRAPHENE PREPARED THEREBY
  申请人：JEON In Yup

  公开号：US20120149897A1

  公开（公告）日：2012-06-14

  The present invention relates to a method of preparing a nitrogen-doped graphene comprising preparing a Edge-Functionalized Graphene by binding a graphite with a organic material having amino groups and functional groups such as carboxy acid group through an electrophilic substitution reaction, and heat treating the resultant Edge-Functionalized Graphene, and a nitrogen-doped graphene prepared thereby. According to the present invention, by a more inexpensive and simpler method, a nitrogen-doped graphene can be prepared at higher purity and higher yield. The nitrogen-doped graphene obtained by the present invention has very excellent physical and electric properties, and particularly has a superior oxygen reduction capability, compared with the platinum catalyst used at cathode of a H 2 /O 2 fuel cell so that it will replace the platinum to lower more the cost of a H 2 /O 2 fuel cell or to increase its life and further to provide a new turning point for the commercialization of a H 2 /O 2 fuel cell.
• US6586555B1
  申请人：——

  公开号：US6586555B1

  公开（公告）日：2003-07-01