硅烷,[1,3,5-苯三基三(氧代)]三[三甲基- | 10586-12-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 硅烷,[1,3,5-苯三基三(氧代)]三[三甲基-
• 英文名称: phloroglucinol tris(trimethylsilyl) ether
• 英文别名: 1,3,5-tris((trimethylsilyl)oxy)benzene；1,3,5-Tris(trimethylsiloxy)benzene；[3,5-bis(trimethylsilyloxy)phenoxy]-trimethylsilane
• CAS: 10586-12-6
• 化学式: C₁₅H₃₀O₃Si₃
• 分子量: 342.658
• InChiKey: PXHSJMJQTOFLAS-UHFFFAOYSA-N

物化性质

• 沸点：
  280-281 °C
• 密度：
  0.931±0.06 g/cm3(Predicted)
• 保留指数：
  1654

计算性质

• 辛醇/水分配系数(LogP)：
  5.33
• 重原子数：
  21
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• 海关编码：
  2931900090

反应信息

• 作为反应物：
  描述：

  硅烷,[1,3,5-苯三基三(氧代)]三[三甲基- 在 甲醇 作用下， 反应 0.33h， 以87%的产率得到间苯三酚
  参考文献：
  名称：

  Nanocrystalline TiO2–HClO4 as a new, efficient and recyclable catalyst for the chemoselective trimethylsilylation of alcohols, phenols and deprotection of silyl ethers

  摘要：

  TiO2-HCIO4, as a new solid acid, was found to be an efficient catalyst for the chemoselective trimethylsilylation of alcohols and phenols. Deprotection of the resulting trimethylsilylethers was achieved using the same catalyst in methanol solvent. The synthesized catalyst was characterized by FT-IR, SEM, TEM, BET and XRD analyses. Our novel synthetic method has the advantages of high yields, short reaction times, low cost and recyclability of the catalyst, simplicity and easy work-up compared to the conventional methods reported in the literature. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.catcom.2011.11.002
• 作为产物：
  描述：

  间苯三酚 、 六甲基二硅氮烷 在 poly(4-vinylpyridine) 作用下， 以 乙腈 为溶剂， 反应 0.08h， 以99%的产率得到硅烷,[1,3,5-苯三基三(氧代)]三[三甲基-
  参考文献：
  名称：

  Poly(4-vinylpyridine) catalyzed chemoselective O-TMS protection of alcohols and phenols and N-Boc protection of amines

  摘要：

  多（4-乙烯基吡啶）（PVP）作为选择性和高效的三甲基硅烷化醇和酚与六甲基二硅氮烷（HMDS）以及胺的N-叔丁氧羰基化与双（叔丁氧羰基）氧化物（Boc）2O的催化剂，具有高效和可重复使用的特性。所有反应都在温和条件下进行，产率为良好至高水平。

  DOI：

  10.1007/s13738-011-0060-5

文献信息

• Partition coefficients of ketones, phenols, aliphatic and aromatic acids, and esters in n-hexane/nitromethane
  作者：Urszula Kotowska、Valery Isidorov

  DOI：10.2478/s11532-011-0060-4

  日期：2011.10.1

  in sample preparation and in countercurrent and liquid-liquid chromatographic separations. Partition coefficients are widely used in toxicology, environmental, and analytical chemistry. The K hn determination procedure for the n -hexane/nitromethane system was optimized and partition coefficients for 99 ketones, esters and trimethylsilyl derivatives of phenols, aliphatic and aromatic acids were determined

  液-液分配用于样品制备以及逆流和液-液色谱分离。分配系数被广泛用于毒理学，环境和分析化学中。该 ķ HN 用于确定过程 Ñ 正己烷/硝基甲烷体系进行了优化和分配系数为99酮，酯和酚的三甲基甲硅烷衍生物，测定脂族和芳族酸。对于130种化合物， 使用 K hn 与其他理化和结构参数之间的数学关系来预测 K hn 值 。
• Multicyclic Poly(ether sulfone)s of Phloroglucinol Forming Branched and Cross-Linked Architectures
  作者：Hans R. Kricheldorf、Detlev Fritsch、Lali Vakhtangishvili、Gert Schwarz

  DOI：10.1021/ma021569i

  日期：2003.6.1

  of linear oligomers due to numerous side reactions. In contrast, polycondensations of silylated phloroglucinol under similar conditions were not plagued by such side reactions but involved various cyclization reactions with high efficiency. The MALDI−TOF mass spectra revealed the formation of various cyclic, bicyclic, and multicyclic species of complex structure up to 12 000 Da. Therefore, cross-linking

  钾2 CO 3DMSO中的间苯三酚和4,4'-二氟二苯砜（DFDPS）促进的缩聚反应会由于许多副反应而生成线性低聚物的混合物。相反，在类似条件下甲硅烷基间苯三酚的缩聚反应不会受到此类副反应的困扰，但会涉及各种高效的环化反应。MALDI-TOF质谱揭示了高达12 000 Da的各种复杂结构的环状，双环和多环物种的形成。因此，仅当添加大量过量（+ 30mol％）的DFDPS时才发生交联。所得的支链和交联聚合物主要由环状结构单元组成。由于环化程度高，试图通过将侧基OH基团与磺内酯烷基化引入磺酸基团仅产生了中等程度的取代。
• Influence of fluorination on CO₂ adsorption in materials derived from fluorinated covalent triazine framework precursors
  作者：Zhenzhen Yang、Song Wang、Zihao Zhang、Wei Guo、Kecheng Jie、Mohamed I. Hashim、Ognjen Š. Miljanić、De-en Jiang、Ilja Popovs、Sheng Dai

  DOI：10.1039/c9ta02573a

  日期：——

  Give me more fluorines: introduction of fluorine in the structure of Covalent Triazine Frameworks can improve their CO₂ adsorption. Materials with optimal fluorine content and narrow nanopore distribution are promising CO₂ scavengers.

  给我更多的氟元素：在共价三嗪骨架的结构中引入氟元素可以提高它们对CO₂的吸附能力。具有最佳氟含量和狭窄纳米孔分布的材料是有前途的CO₂清除剂。
• Surpassing Robeson Upper Limit for CO2/N2 Separation with Fluorinated Carbon Molecular Sieve Membranes
  作者：Zhenzhen Yang、Wei Guo、Shannon Mark Mahurin、Song Wang、Hao Chen、Long Cheng、Kecheng Jie、Harry M. Meyer、De-en Jiang、Gongping Liu、Wanqin Jin、Ilja Popovs、Sheng Dai

  DOI：10.1016/j.chempr.2019.12.006

  日期：2020.3

  triazine units, fluorine, and ether groups, these carbon molecular sieve membranes obtained after pyrolysis exhibit intrinsic ultra-micropores, high surface areas and excellent thermal stability under air. Excellent CO2 permeability and CO2 to N2 selectivity surpassing the Robeson upper bound are achieved. Our general design and synthesis protocol allow an easy access to fluorinated porous membranes, thus

  粉末状氟化三嗪骨架的亲CO 2特性使其成为制造多孔CO 2分离膜的有希望的候选者。由于缺乏合适的合成方法，很少报道。在这里，基于共价三嗪骨架的氟化膜是通过溶胶-凝胶聚合工艺合理设计含有氟和醚基的芳族腈单体而制备的。随着膜中氟的含量，CO 2分离性能显着提高。具有功能化的三嗪单元，氟和醚基，热解后获得的这些碳分子筛膜表现出固有的超微孔，高表面积和在空气中的出色热稳定性。优秀的CO获得了超过Robeson上限的2渗透率和CO 2 -N 2选择性。我们的一般设计和合成方案可轻松访问氟化多孔膜，从而显着扩展了目前有限的亲CO 2和化学稳定膜库，可实现高效CO 2分离。
• Preparation, characterization and use of 3-methyl-1-sulfonic acid imidazolium hydrogen sulfate as an eco-benign, efficient and reusable ionic liquid catalyst for the chemoselective trimethylsilyl protection of hydroxyl groups
  作者：Nader Ghaffari Khaligh

  DOI：10.1016/j.molcata.2011.08.021

  日期：2011.10

  New and novel ionic liquid (3-methyl-1-sulfonic acid imidazolium hydrogen sulfate) is a recyclable and eco-benign catalyst for the chemoselective trimethylsilyl protection of hydroxyl groups under solvent-free conditions to afford trimethylsilanes in excellent yields (92-100%) and in very short reaction times (1-8 min). The catalyst was characterized by FT-IR, H-1 NMR and C-13 NMR studies. All the products were extensively characterized by H-1 NMR, IR, GC-MS and melting point analyses. A mechanism for the catalytic activity is proposed. The catalyst can be recovered and reused without loss of activity. The work-up of the reaction consists of a simple separation, followed by concentration of the crude product and purification. (C) 2011 Elsevier B.V. All rights reserved.

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