(η5-1-trifluoromethyl-2,3,4,5-tetramethylcyclopentadienyl)bis(acetonitrile)(triphenylphosphine)ruthenium hexafluorophosphate | 406502-48-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (η5-1-trifluoromethyl-2,3,4,5-tetramethylcyclopentadienyl)bis(acetonitrile)(triphenylphosphine)ruthenium hexafluorophosphate
• 英文别名: acetonitrile;ruthenium(2+);1,2,3,4-tetramethyl-5-(trifluoromethyl)cyclopenta-1,3-diene;triphenylphosphane;hexafluorophosphate
• CAS: 406502-48-5
• 化学式: C₃₂H₃₃F₃N₂PRu*F₆P
• 分子量: 779.631
• InChiKey: GMSAAGOTSKXLFR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (η5-1-trifluoromethyl-2,3,4,5-tetramethylcyclopentadienyl)tris(acetonitrile)ruthenium hexafluorophosphate 、 三苯基膦 以 二氯甲烷 为溶剂， 以62%的产率得到(η5-1-trifluoromethyl-2,3,4,5-tetramethylcyclopentadienyl)bis(acetonitrile)(triphenylphosphine)ruthenium hexafluorophosphate
  参考文献：
  名称：

  A Facile Route to 1-Trifluoromethyl-2,3,4,5-tetramethylcyclopentadienyl Ruthenium Half- and Mixed-Sandwich Compounds

  摘要：

  A series of half and mixed-sandwich (Cpdouble dagger = 1-trifluoromethyl-2,3,4,5-tetramethylcyclopentadienide) ruthenium compounds have been synthesized from a new Cpdouble daggerRu synthon, [Cpdouble daggerRu(NCCH3)(3)](PF6). [Cpdouble daggerRu(NCCH3)(3)](PF6) is efficiently generated by photolysis of [Cpdouble daggerRuBz](PF6) in acetonitrile with a quantum yield of approximately 0.34. The methods described here should be useful for the synthesis of other compounds that contain the Cpdouble daggerRu group.

  DOI：

  10.1021/om010863g