[Cu(1-hydroxycyclohexanephosphonic acid(-2H))(H2O)2]2 | 839715-98-9

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦及其衍生物
• 英文名称: [Cu(1-hydroxycyclohexanephosphonic acid(-2H))(H2O)2]2
• CAS: 839715-98-9
• 化学式: C₁₂H₃₀Cu₂O₁₂P₂
• 分子量: 555.403
• InChiKey: KKQMLQBCGGHALL-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  copper(II) nitrate trihydrate 、 1-hydroxycyclohexanephosphonic acid 以 水 为溶剂， 以45%的产率得到[Cu(1-hydroxycyclohexanephosphonic acid(-2H))(H2O)2]2
  参考文献：
  名称：

  Copper phosphonates with dinuclear and layer structures: a structural and magnetic study

  摘要：

  Hydrothermal reactions of copper (II) nitrate with 1-hydroxycyclohexanephosphonic acid [C6H10(OH)PO3H2] or Delta(1)-cyclohexenephosphonic acid [C6H9PO3H2] have resulted in three new copper phosphonates, namely, Cu(C6H10(OH)PO3)(H2O)(2) (1), Cu(C6H10(OH)PO3) (2) and Cu(C6H9PO3)(H2O) (3). Compound 1 has a dinuclear structure in which two {CuO5} square pyramids are bridged by two {CPO3} tetrahedra through corner sharing. The dimers are connected through intermolecular hydrogen bonds, forming supramolecular layers. Both compounds 2 and 3 show layer structures typical for metal mono-phosphonates, in which the inorganic metal-containing layers are separated by cyclohexane or cyclohexene groups. The magnetic studies show that ferromagnetic interactions are mediated between copper centers in compound 1. In compounds 2 and 3, antiferromagnetic interactions are dominant. (C) 2004 Elsevier Inc. All rights reserved.

  DOI：

  10.1016/j.jssc.2004.09.007