N'-di-s-butyl-p-phenylenediamine | 69796-47-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N'-di-s-butyl-p-phenylenediamine
• 英文别名: 4-N,4-N-di(butan-2-yl)benzene-1,4-diamine
• CAS: 69796-47-0
• 化学式: C₁₄H₂₄N₂
• 分子量: 220.35
• InChiKey: BFVOBXSKECUHSW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  16
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  29.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为试剂：
  描述：

  甲基丙烯酸甲酯 、 N-羟乙基-2-吡咯烷酮 在 4-甲氧基苯酚 、 N'-di-s-butyl-p-phenylenediamine Tripotassium;phosphate 、 甲基丙烯酸甲酯 、 crude product 作用下， 63.0~130.0 ℃ 、17.33 kPa 条件下， 反应 5.33h， 以afforded the product of value (130° C., 1.3 mbar)的产率得到N-hydroxyethylpyrrolidone methacrylate
  参考文献：
  名称：

  CATALYTIC PROCESS FOR PREPARING (METH)ACRYLATES FROM N-HYDROXYALKYLATED LACTAMS

  摘要：

  催化制备N-羟基烷基内酰胺(meth)丙烯酸酯的过程及其应用。

  公开号：

  US20070123673A1

文献信息

• Reversibly Thermochromic Compositions
  申请人：Fischer Walter

  公开号：US20090302284A1

  公开（公告）日：2009-12-10

  The present invention pertains to a reversibly thermochromic system comprising a substituted or an unsubstituted 6,11-dihydroxy-naphthacene-5,12-dione and a base and to a reversibly thermochromic composition comprising the reversibly thermochromic system and a carrier material and to novel substituted 6,11-dihydroxy-naphthacene-5,12-diones.

  本发明涉及一种可逆热致变色系统，包括取代或未取代的6,11-二羟基萘并[5,12-二酮]和一种碱，以及一种可逆热致变色组合物，包括可逆热致变色系统和载体材料，还涉及新型的取代的6,11-二羟基萘并[5,12-二酮]。
• STERICALLY HINDERED AMINE STABILIZER
  申请人：Menozzi Edoardo

  公开号：US20120232197A1

  公开（公告）日：2012-09-13

  The present invention relates to oxygen-substituted sterically hindered amines of the formulae I or II: (II), wherein, for example, F 2 , R 3 , R 5 , R 6 , R 8 , R 9 , R 11 , R 12 , R 13 , R 14 are n-butyl; Z 1 to Z 10 are propoxy and R 1 , R 4 , R 7 , R 10 , R 13 are 2,2,6,6-tetramethyl-1-propoxy-piperidin-4-yl. Compositions comprising compounds of formulae I or II and an organic material, which is susceptible to oxidative, thermal or light-induced degradation, are further disclosed. Optionally, further additives are contained.

  本发明涉及公式I或II的含氧立体阻碍胺化合物：（II），其中，例如，F2，R3，R5，R6，R8，R9，R11，R12，R13，R14为正丁基；Z1至Z10为丙氧基，而R1，R4，R7，R10，R13为2,2,6,6-四甲基-1-丙氧基哌啶-4-基。此外，还公开了包含公式I或II化合物和易于氧化、热降解或光诱导降解的有机材料的组合物。可选地，还包含其他添加剂。
• Method and compositions for inhibiting polymerization of acrylic acid monomers
  申请人：BETZ EUROPE, INC.

  公开号：EP0398633A1

  公开（公告）日：1990-11-22

  A method of inhibiting acid monomer (as hereinbefore defined) polymerization comprising adding to the monomer (a) a manganese source compound and (b) a phenylenediamine compound having at least one N-H bond therein. Acrylic acid (as hereinbefore defined) anti-polymerization composition comprising a liquid carrier and dissolved or dispersed therein (a) a manganese source compound and (b) a phenylenediamine compound having at least one N-H bond therein.

  一种抑制酸性单体(如前定义)聚合的方法，包括向单体中加入(a)锰源化合物和(b)其中至少有一个N-H键的苯二胺化合物。 丙烯酸（如前所述）防聚合组合物，包括液体载体和溶解或分散于其中的(a)锰源化合物和(b)至少有一个N-H键的苯二胺化合物。
• Compositions and methods for inhibiting vinyl aromatic monomer polymerization
  申请人：BETZ EUROPE, INC.

  公开号：EP0690117A2

  公开（公告）日：1996-01-03

  Compositions and methods for inhibiting polymerization of vinyl aromatic monomers in oxygen-free processing systems are disclosed. The compositions comprise an oxime compound and a hydroxylamine compound and, alternatively, an oxime compound or a dinitrophenol, a hydroxylamine compound and a phenylenediamine compound. The methods comprise adding one of the compositions to the vinyl aromatic monomer in an amount ranging from 1 to about 10,000 parts per million parts monomer. An improved method for inhibiting the polymerization of vinyl aromatic monomers with a hydroxylamine compound is also disclosed. The improvement provides for adding a catalytic amount of a phenylenediamine compound to the vinyl aromatic monomer system while replacing any phenylenediamine compound lost as a result of physical removal from the system via the waste stream.

  本发明公开了在无氧加工系统中抑制乙烯基芳香族单体聚合的组合物和方法。这些组合物包括肟化合物和羟胺化合物，或者肟化合物或二硝基苯酚、羟胺化合物和苯二胺化合物。这些方法包括向乙烯基芳香族单体中加入其中一种组合物，加入量为每百万份单体 1 至约 10,000 份。此外，还公开了一种用羟胺化合物抑制乙烯基芳香族单体聚合的改进方法。该改进方法可向乙烯基芳香族单体体系中添加催化量的苯二胺化合物，同时取代因通过废液从体系中物理去除而损失的任何苯二胺化合物。
• New indoaniline metal complex, process for their production, and transparent recording medium and optical recording medium by use thereof
  申请人：NIPPON PAPER INDUSTRIES CO., LTD.

  公开号：EP0737722A2

  公开（公告）日：1996-10-16

  An indoaniline metal complex of formula 1 or formula 2 having a large absorption in the near-infrared range and a reduced absorption in the visible range, which indoaniline metal complex is used in a transparent recording medium: [CHEMICAL FORMULA 1] [CHEMICAL FORMULA 2] where M is a metal atom, and X is a negative ion.

  一种式 1 或式 2 的吲哚苯胺金属络合物，在近红外范围内具有较大的吸收率，在可见光范围内的吸收率较低，该吲哚苯胺金属络合物用于透明记录介质： [化学式 1］ [化学式 2］ 其中 M 是金属原子，X 是负离子。