nickel(II)(5-methyloxazolidine-4-carboxylate) | 136899-97-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧唑烯
• 英文名称: nickel(II)(5-methyloxazolidine-4-carboxylate)
• CAS: 136899-97-3
• 化学式: C₁₀H₂₀N₂NiO₈
• 分子量: 354.967
• InChiKey: KUVPJCIBBSLHCL-YJIALISYSA-L

反应信息

• 作为反应物：
  描述：

  nickel(II)(5-methyloxazolidine-4-carboxylate) 以 neat (no solvent, solid phase) 为溶剂， 生成 nickel(II)(5-methyloxazolidine-4-carboxylate)
  参考文献：
  名称：

  Synthesis and structural studies of some metal(II) complexes of 5-methyloxazolidine-4-carboxylic acid

  摘要：

  The reactions of formaldehyde with the metal(II) chelates of L-threonine (metal = copper, nickel, cobalt and zinc) result in the formation of the metal(II) complexes of 5-methyloxazolidine-4-carboxylic acid. The copper(II) complex, C10H20N2O8Cu, is obtained from the recrystallization of its 3-hydroxymethyl derivative, C12H24N2O10Cu, which initially forms. C10H20N2O8Cu crystallizes in the orthorhombic space group P2(1)2(1)2(1) with a = 8.166(1), b = 8.936(1), c = 20.463(5) angstrom and Z = 4. The structure has been refined to R = 0.021 and R(w) = 0.021 based on 1444 reflections with l > 2.5-sigma-(l). The geometry about copper is based on a square pyramid with a coordinated water in the apical position. The synthesized compounds are characterized by microanalysis, magnetic and thermal data as well as examinations of their electronic and infrared spectra.

  DOI：

  10.1016/s0020-1693(00)82990-4
• 作为产物：
  描述：

  bis(L-threoninato)nickel(II) 在 formaldehyde 作用下， 以 水 为溶剂， 以60%的产率得到nickel(II)(5-methyloxazolidine-4-carboxylate)
  参考文献：
  名称：

  Synthesis and structural studies of some metal(II) complexes of 5-methyloxazolidine-4-carboxylic acid

  摘要：

  The reactions of formaldehyde with the metal(II) chelates of L-threonine (metal = copper, nickel, cobalt and zinc) result in the formation of the metal(II) complexes of 5-methyloxazolidine-4-carboxylic acid. The copper(II) complex, C10H20N2O8Cu, is obtained from the recrystallization of its 3-hydroxymethyl derivative, C12H24N2O10Cu, which initially forms. C10H20N2O8Cu crystallizes in the orthorhombic space group P2(1)2(1)2(1) with a = 8.166(1), b = 8.936(1), c = 20.463(5) angstrom and Z = 4. The structure has been refined to R = 0.021 and R(w) = 0.021 based on 1444 reflections with l > 2.5-sigma-(l). The geometry about copper is based on a square pyramid with a coordinated water in the apical position. The synthesized compounds are characterized by microanalysis, magnetic and thermal data as well as examinations of their electronic and infrared spectra.

  DOI：

  10.1016/s0020-1693(00)82990-4