C4H4NO2Ag*2Ph3P | 1159614-04-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: C4H4NO2Ag*2Ph3P
• 英文别名: [(Ph3P)2Ag(Mal)]；(succinimide)Ag(PPh3)2
• CAS: 1159614-04-6
• 化学式: C₄₀H₃₄AgNO₂P₂
• 分子量: 730.531
• InChiKey: TZZHFDGEAMEGPP-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N-silver(I) succinimide 、 三苯基膦 以 二氯甲烷 为溶剂， 以96%的产率得到C4H4NO2Ag*2Ph3P
  参考文献：
  名称：

  Synthesis and characterization of organophosphine/phosphite stabilized N-silver(I) succinimide: crystal structure of [(Ph3P)3·AgNC4H4O2]

  摘要：

  Six organophosphite stabilized N-silver(I) succinimide complexes of the type Ln center dot AgNC4H4O2 (L=PPh3; n=1, 2a; n =2, 2b; n =3, 2c; L=P(OEt)(3); n=1, 2d; n=2, 2e; n =3, 2f) have been prepared by reacting (AgNC4O2], which can be synthesized from succinimide and excessive Ag2O in boiling water, with triphenylphospine or triethylphosphite in dichloromethane under a nitrogen atmosphere. These complexes were obtained in high yield and characterized by elemental analysis. H-1, C-13(H) NMR, IR spectroscopy and thermal analysis (TG and DSC). The molecular structure of 2c has been determined by X-ray single crystal analysis, in which the silver atom is in distorted tetrahedral geometry. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.02.021

文献信息

• Lewis-Base Stabilized N-Silver(I) Succinimide Complexes: Synthesis, Crystal Structures and Their Use as CVD-Precursors
  作者：Xian Tao、Ke-Cheng Shen、Yu-Long Wang、Ying-Zhong Shen

  DOI：10.1002/zaac.201100072

  日期：2011.8

  succinimide complexes of type [Ln·Rm·AgNC4H4O2] (L = N,N,N′,N′-tetramethylethylenediamine (TMEDA), n = 1, m = 0, 2a; L = P(OEt)3, n = 2, m = 0, 2b; L = PPh3, m = 0, n = 2, 2c; L = P(OMe)3, R = TMEDA, n = 1, m = 1, 2d) were prepared by a “one-pot” synthesis methodology and characterized. The molecular structures of 2a and 2c have been determined by using X-ray single crystal analysis. Complex 2a exists

  四种 [Ln·Rm·AgNC4H4O2] 型路易斯碱稳定的 N-银 (I) 琥珀酰亚胺配合物 (L = N,N,N',N'-四甲基乙二胺 (TMEDA), n = 1, m = 0, 2a; L = P(OEt)3, n = 2, m = 0, 2b; L = PPh3, m = 0, n = 2, 2c; L = P(OMe)3, R = TMEDA, n = 1, m = 1, 2d) 是通过“一锅”合成方法制备和表征的。2a 和2c 的分子结构已通过X 射线单晶分析确定。配合物 2a 以离子对 [Ag(TMEDA)2]+[Ag(NC4H4O2)2]-} 的形式存在，配合物 2c 是具有三配位银原子的单体。使用MOCVD技术首次将配合物2b用作前驱体沉积银。使用扫描电子显微镜 (SEM) 和能量色散 X 射线分析 (EDX) 对获得的银膜进行表征。
• An organo-silver compound that shows antimicrobial activity against Pseudomonas aeruginosa as a monomer and plasma deposited film
  作者：Neil Poulter、Xavier Munoz-Berbel、Andrew L. Johnson、Andrea J. Dowling、Nicholas Waterfield、A. Tobias A. Jenkins

  DOI：10.1039/b915467a

  日期：——

  In this communication we describe the synthesis, characterisation and plasma deposition of a novel organo-silver compound for the prevention of the growth of Pseudomonas aeruginosa on both polystyrene surfaces and polypropylene non-woven fabrics.

  在这篇论文中，我们描述了一种新型有机银化合物的合成、表征和等离子沉积，该化合物可用于防止铜绿假单胞菌在聚苯乙烯表面和聚丙烯无纺布上生长。