[Cu(3-pyridylmethylsalicylideneimino)2] | 1060717-18-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Cu(3-pyridylmethylsalicylideneimino)2]
• CAS: 1060717-18-1
• 化学式: C₂₆H₂₂CuN₄O₂
• 分子量: 486.032
• InChiKey: YRLCFAOMOFNYJL-ZQSWXEMLSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Cu(3-pyridylmethylsalicylideneimino)2] 、 copper(II) perchlorate 以 甲醇 、 二氯甲烷 为溶剂， 以85%的产率得到[Cu(Cu(3-pyridylmethylsalicylideneimino)2)2](ClO4)2
  参考文献：
  名称：

  Assembly molecular architectures based on structural variation of metalloligand [Cu(PySal)2] (PySal=3-pyridylmethylsalicylideneimino)

  摘要：

  A versatile neutral metalloligand [Cu(PySal)(2)] (1) (PySal = 3-pyridylmethylsalicylidene-imino) was exploited as a building unit to construct five complexes {Cu[Cu(PySal)(2)](2)}(ClO4)(2) (2), [Cd[Cu(PySal)(2)](2)(H2O)(2)]) (NO3)(2) center dot 2H(2)O center dot 4CH(3)OH (3), {Zn[mu(2)-Cu(PySal)(2)]Cl-2}(n) center dot nCH(3)OH (4). {Hg[mu(2)-Cu(PySal)(2)]l(2)}(n) (5) and {Cd[mu(2)-Cu(PySal)(2)]Cl-2}n center dot nCH(2)Cl(2) (6). [Cu(FySal)(2)] acts as a chelating ligand in discrete complexes 2 and 3 with unbound anions, but as a bis-monodentate bridging ligand in polymers 4, 5 and 6 when halogen anions coordinated cooperatively to metal cations. The coordination geometry of Cu2+ is well-defined square planar in bridging [Cu(PySal)(2)], analogous to that in free metalloligand (1), but it is distorted square planar in chelating [Cu(PySal)(2)]. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.05.005
• 作为产物：
  描述：

  copper(II) acetate monohydrate 、 N-salicylidene-3-(aminomethyl)pyridine 以 甲醇 、 二氯甲烷 为溶剂， 以85%的产率得到[Cu(3-pyridylmethylsalicylideneimino)2]
  参考文献：
  名称：

  Assembly molecular architectures based on structural variation of metalloligand [Cu(PySal)2] (PySal=3-pyridylmethylsalicylideneimino)

  摘要：

  A versatile neutral metalloligand [Cu(PySal)(2)] (1) (PySal = 3-pyridylmethylsalicylidene-imino) was exploited as a building unit to construct five complexes {Cu[Cu(PySal)(2)](2)}(ClO4)(2) (2), [Cd[Cu(PySal)(2)](2)(H2O)(2)]) (NO3)(2) center dot 2H(2)O center dot 4CH(3)OH (3), {Zn[mu(2)-Cu(PySal)(2)]Cl-2}(n) center dot nCH(3)OH (4). {Hg[mu(2)-Cu(PySal)(2)]l(2)}(n) (5) and {Cd[mu(2)-Cu(PySal)(2)]Cl-2}n center dot nCH(2)Cl(2) (6). [Cu(FySal)(2)] acts as a chelating ligand in discrete complexes 2 and 3 with unbound anions, but as a bis-monodentate bridging ligand in polymers 4, 5 and 6 when halogen anions coordinated cooperatively to metal cations. The coordination geometry of Cu2+ is well-defined square planar in bridging [Cu(PySal)(2)], analogous to that in free metalloligand (1), but it is distorted square planar in chelating [Cu(PySal)(2)]. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.05.005