2-N,N-Dimethylamino-4,5-dihydrophenanthreno<3,4-d>-1,3-dithiol | 154109-43-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 2-N,N-Dimethylamino-4,5-dihydrophenanthreno<3,4-d>-1,3-dithiol
• CAS: 154109-43-0
• 化学式: C₁₇H₁₇NS₂
• 分子量: 299.461
• InChiKey: IHBDHDASQJRLJS-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  2-N,N-Dimethylamino-4,5-dihydrophenanthreno<3,4-d>-1,3-dithiol 在 高氯酸 、 三乙胺 作用下， 以 乙醇 、 丙酮 为溶剂， 反应 1.5h， 生成 2-(4,5-Dihydrophenanthreno<3,4-d>-1,3-dithiol-2-yliden)-4,5-dihydrophenanthreno<3,4-d>-1,3-dithiol
  参考文献：
  名称：

  Tetrathiafulvalene. XXVII [1] Darstellung und Eigenschaften cis- und trans-isomerer Dihydrophenanthreno-Tetrathiafulvalene

  摘要：

  The synthesis of anellated tetrathiafulvalenes (TTF) 10a-c, 11a-b via the 1,3-dithiolium salt/triethylamin or 1,3-dithiole-2-thione/triethyl phosphite route is described. The dihydrophenanthreno-anellated TITs 10a, b can be thermally transformed into the phenanthreno-anellated TTFs 11a, b. Only in the case of the dihydrophenanthreno-anellated TTF 10b (with ''alpha-naphthyl structure'') the isolation of the cis- and trans-isomer was possible due to differences in the solubility. Starting from the pure cis- or trans-isomer the radical salts of 10b are reducible to a 1 : 1 mixture of the cis/trans stereo isomers. The spectroscopic, electrochemical, and conductivity properties of the synthesized TTFs and their complexes with iodine, TCNQ, and DDQ are described.

  DOI：

  10.1002/prac.19933350705
• 作为产物：
  描述：

  2-N,N-Dimethylamino-4,5-dihydrophenanthreno<3,4-d>-1,3-dithioliumperchlorat 在 sodium tetrahydroborate 作用下， 以 乙醇 为溶剂， 反应 2.0h， 生成 2-N,N-Dimethylamino-4,5-dihydrophenanthreno<3,4-d>-1,3-dithiol
  参考文献：
  名称：

  Tetrathiafulvalene. XXVII [1] Darstellung und Eigenschaften cis- und trans-isomerer Dihydrophenanthreno-Tetrathiafulvalene

  摘要：

  The synthesis of anellated tetrathiafulvalenes (TTF) 10a-c, 11a-b via the 1,3-dithiolium salt/triethylamin or 1,3-dithiole-2-thione/triethyl phosphite route is described. The dihydrophenanthreno-anellated TITs 10a, b can be thermally transformed into the phenanthreno-anellated TTFs 11a, b. Only in the case of the dihydrophenanthreno-anellated TTF 10b (with ''alpha-naphthyl structure'') the isolation of the cis- and trans-isomer was possible due to differences in the solubility. Starting from the pure cis- or trans-isomer the radical salts of 10b are reducible to a 1 : 1 mixture of the cis/trans stereo isomers. The spectroscopic, electrochemical, and conductivity properties of the synthesized TTFs and their complexes with iodine, TCNQ, and DDQ are described.

  DOI：

  10.1002/prac.19933350705