8,19-Bis(2-decyltetradecyl)-13,24-dioctyl-8,19-diazanonacyclo[15.11.1.16,26.02,15.03,12.04,27.05,10.021,29.023,28]triaconta-1(29),2,4,6(30),10,12,14,16,21,23,25,27-dodecaene-7,9,18,20-tetrone | 909019-80-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: 8,19-Bis(2-decyltetradecyl)-13,24-dioctyl-8,19-diazanonacyclo[15.11.1.16,26.02,15.03,12.04,27.05,10.021,29.023,28]triaconta-1(29),2,4,6(30),10,12,14,16,21,23,25,27-dodecaene-7,9,18,20-tetrone
• CAS: 909019-80-3
• 化学式: C₉₂H₁₃₈N₂O₄
• 分子量: 1336.12
• InChiKey: LQRCKJPZWSQIEL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  37.1
• 重原子数：
  98
• 可旋转键数：
  58
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  74.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  N,N'-bis(2-decyl-tetradecyl)-1,7-dibromo-3,4,9,10-perylene diimide 、 1-癸炔 在 四(三苯基膦)钯 copper(l) iodide 、 三乙胺 、 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 甲苯 为溶剂， 反应 64.0h， 以86%的产率得到8,19-Bis(2-decyltetradecyl)-13,24-dioctyl-8,19-diazanonacyclo[15.11.1.16,26.02,15.03,12.04,27.05,10.021,29.023,28]triaconta-1(29),2,4,6(30),10,12,14,16,21,23,25,27-dodecaene-7,9,18,20-tetrone
  参考文献：
  名称：

  Coronene charge-transport materials, methods of fabrication thereof, and methods of use thereof

  摘要：

  简而言之，本公开的实施例包括葵花烯电荷传输材料、形成葵花烯电荷传输材料的方法，以及使用葵花烯电荷传输材料的方法。

  公开号：

  US08039625B2

文献信息

• Room-temperature discotic liquid-crystalline coronene diimides exhibiting high charge-carrier mobility in air
  作者：Zesheng An、Junsheng Yu、Benoit Domercq、Simon C. Jones、Stephen Barlow、Bernard Kippelen、Seth R. Marder

  DOI：10.1039/b910898j

  日期：——

  Six N,N′,5,11-tetrasubstituted coronene-2,3,8,9-tetracarboxydiimides have been synthesised incorporating 3,4,5-tri(n-dodecyloxy)phenyl or 2-(n-decyl)-n-tetradecyl groups in various positions. Differential scanning calorimetry, polarised optical microscopy, and X-ray diffraction indicate that all form columnar discotic mesophases from around room temperature to around 200 °C. Charge-carrier mobility values, which energetic considerations suggest are electron mobility values, have been determined in non-aligned samples cooled from the isotropic melt using the space-charge-limited current technique. The highest mobility, 6.7 cm2V−1 s−1, was found in N,N′-bis(n-2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecylfluorooctyl)-5,11-bis(3-[3,4,5-tri(n-dodecyloxy)phenyl}carbonyloxy]-n-propyl)coronene-2,3,8,9-tetracarboxydiimide, which X-ray diffraction suggests is the most highly ordered of the materials examined.

  已合成六种N,N′,5,11-四取代的二萘-2,3,8,9-四羧二亚胺，分别在不同位置引入了3,4,5-三(n-十二烷氧基)苯基或2-(n-癸基)-n-十四烷基团。差示扫描热量测量、偏振光学显微镜和X射线衍射表明，这些化合物在近室温到约200°C的范围内均形成柱状盘状介相。通过空间电荷限制电流技术，在从各向同性熔体冷却的非对齐样品中测定了载流子迁移率值，热力学考虑表明这些值是电子迁移率的值。最高迁移率为6.7 cm²V⁻¹ s⁻¹，出现在N,N′-双(n-2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-十五烷基氟辛基)-5,11-双(3-[3,4,5-三(n-十二烷氧基)苯基}羧氧]-n-丙基)二萘-2,3,8,9-四羧二亚胺中，X射线衍射表明这是所研究材料中有序度最高的。
• CORONENE CHARGE-TRANSPORT MATERIALS, METHODS OF FABRICATION THEREOF, AND METHODS OF USE THEREOF
  申请人：Marder Seth

  公开号：US20090044863A1

  公开（公告）日：2009-02-19

  Briefly described, embodiments of this disclosure include coronene charge-transport materials, methods of forming coronene charge-transport materials, and methods of using the coronene charge-transport materials.
• US8039625B2
  申请人：——

  公开号：US8039625B2

  公开（公告）日：2011-10-18