4'4'-双(10H-吩恶嗪-10-基)甲酮 | 1618669-35-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 4'4'-双(10H-吩恶嗪-10-基)甲酮
• 英文名称: 4,4’-bis(10H-phenoxazin-10-yl)methanone
• 英文别名: Bis(4-(10H-phenoxazin-10-yl)phenyl)methanone；bis(4-phenoxazin-10-ylphenyl)methanone
• CAS: 1618669-35-4
• 化学式: C₃₇H₂₄N₂O₃
• 分子量: 544.609
• InChiKey: GXAXXCSWPANWPQ-UHFFFAOYSA-N

物化性质

• 沸点：
  713.3±60.0 °C(Predicted)
• 密度：
  1.317±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  9
• 重原子数：
  42
• 可旋转键数：
  4
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  42
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  吩噁嗪 、 4,4'-二氟二苯甲酮 在 potassium tert-butylate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 12.5h， 生成 4'4'-双(10H-吩恶嗪-10-基)甲酮
  参考文献：
  名称：

  POLYCYCLIC COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME

  摘要：

  提供一种多环化合物和包括该化合物的有机发光器件。该多环化合物由Formula1表示：

  公开号：

  US20180240982A1

文献信息

• ORGANOMETALLIC COMPLEX AND APPLICATION THEREOF IN ELECTRONIC DEVICES
  申请人：GUANGZHOU CHINARAY OPTOELECTRONIC MATERIALS LTD.

  公开号：US20190241590A1

  公开（公告）日：2019-08-08

  Disclosed are an organometallic complex comprising a new six-membered N-heterocyclic ligand, and an application thereof in an organic electronic device, especially in a phosphorescent organic light-emitting diode. The present invention further relates to an organic electronic device comprising the organometallic complex according to the present invention, especially an organic light-emitting diode, and an application thereof in display and illumination technology. In the present invention, the device structure is optimized and the concentration of the metal complex in the substrate is changed, so that the device achieves the optimal performance, and an OLED device having high efficiency, high luminance and high stability is achieved, thereby providing a better choice of materials for full-colour display and illumination application.

  揭示了一种含有新的六元N-杂环配体的有机金属络合物，以及其在有机电子器件中的应用，特别是在磷光有机发光二极管中的应用。本发明还涉及一种含有根据本发明的有机金属络合物的有机电子器件，特别是有机发光二极管，以及其在显示和照明技术中的应用。在本发明中，优化了器件结构并改变了基板中金属络合物的浓度，使得器件实现了最佳性能，并实现了具有高效率、高亮度和高稳定性的OLED器件，从而为全彩显示和照明应用提供了更好的材料选择。
• FUSED RING COMPOUND, HIGH POLYMER, MIXTURE, COMPOSITION, AND ORGANIC ELECTRONIC COMPONENT
  申请人：GUANGZHOU CHINARAY OPTELECTRONIC MATERIALS LTD.

  公开号：US20190330152A1

  公开（公告）日：2019-10-31

  Disclosed in the present invention are a fused ring compound and applications thereof in organic electronic components, particularly in organic electroluminescent diodes. Also disclosed in the present invention are an organic electronic component comprising the fused ring compound, and applications thereof in organic electroluminescent diodes and in display and lighting technologies. Further disclosed in the present invention are a formulation comprising the fused ring compound, and applications thereof in the preparation of organic electronic components. By optimizing the component structure, good component performance can be achieved, and especially a high-performance OLED component can be implemented, which provide good material and preparation technology choices for full-color display and lighting applications.

  本发明公开了一种融合环化合物及其在有机电子元件中的应用，特别是在有机电致发光二极管中的应用。本发明还公开了一种包括融合环化合物的有机电子元件，以及其在有机电致发光二极管、显示和照明技术中的应用。本发明还公开了一种包括融合环化合物的配方，并在有机电子元件制备中的应用。通过优化元件结构，可以实现良好的元件性能，特别是可以实现高性能的OLED元件，为全彩显示和照明应用提供了良好的材料和制备技术选择。
• NITROGEN-CONTAINING FUSED HETEROCYCLIC RING COMPOUND AND APPLICATION THEREOF
  申请人：GUANGZHOU CHINAPAY OPTOELECTRONIC MATERIALS LTD.

  公开号：US20200223857A1

  公开（公告）日：2020-07-16

  The present invention relates to a nitrogen-containing fused heterocyclic ring compound and application thereof. The compound has the structural formula (I): using the described compound, it is possible to fabricate a device having higher stability and a longer service life.

  本发明涉及一种含氮融合杂环环化合物及其应用。该化合物具有结构式（I）：利用所述化合物，可以制造具有更高稳定性和更长寿命的设备。
• FUSED RING COMPOUND, HIGH POLYMER, MIXTURE, COMPOSITION AND ORGANIC ELECTRONIC COMPONENT
  申请人：GUANGZHOU CHINARAY OPTOELECTRONIC MATERIALS LTD.

  公开号：US20210114954A1

  公开（公告）日：2021-04-22

  A fused ring compound and applications thereof in organic electronic components, particularly in organic electroluminescent diodes; an organic electronic component comprising the fused ring compound, and applications thereof in organic electroluminescent diodes and in display and lighting technologies; and a formulation comprising the fused ring compound, and applications thereof in the preparation of organic electronic components. By optimizing the component structure, good component performance can be achieved, and especially, a high-performance OLED component can be implemented, which provide good material and preparation technology choices for full-color display and lighting applications.

  一种融合环化合物及其在有机电子元件中的应用，特别是在有机电致发光二极管中的应用；包括该融合环化合物的有机电子元件，在有机电致发光二极管和显示与照明技术中的应用；以及包含该融合环化合物的配方，在有机电子元件的制备中的应用。通过优化元件结构，可以实现良好的元件性能，尤其是可以实现高性能的OLED元件，为全彩显示和照明应用提供了良好的材料和制备技术选择。
• Luminous Butterflies: Efficient Exciton Harvesting by Benzophenone Derivatives for Full‐Color Delayed Fluorescence OLEDs
  作者：Sae Youn Lee、Takuma Yasuda、Yu Seok Yang、Qisheng Zhang、Chihaya Adachi

  DOI：10.1002/anie.201402992

  日期：2014.6.16

  Butterfly‐shaped luminescent benzophenone derivatives with small energy gaps between their singlet and triplet excited states are used to achieve efficient full‐color delayed fluorescence. Organic light‐emitting diodes (OLEDs) with these benzophenone derivatives doped in the emissive layer can generate electroluminescence ranging from blue to orange–red and white, with maximum external quantum efficiencies

  在单重态和三重态激发态之间具有较小能隙的蝴蝶形发光二苯甲酮衍生物可用于实现高效的全色延迟荧光。在发光层中掺杂了这些二苯甲酮衍生物的有机发光二极管（OLED）可以产生从蓝色到橙红色和白色的电致发光，最大外部量子效率高达14.3％。三重态激子可通过延迟的荧光通道有效收集。