{PtCl2(AsPh3)(PBu3)} | 135759-11-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: {PtCl2(AsPh3)(PBu3)}
• CAS: 135759-11-4
• 化学式: C₃₀H₄₂AsCl₂PPt
• 分子量: 774.545
• InChiKey: SOVXQIDLHNGBJK-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  [Pt2Cl2(μ-Cl)2(P(n-Bu)3)2] 在 pyridine 作用下， 以 氘代氯仿 、 苯 为溶剂， 生成 {PtCl2(AsPh3)(PBu3)} 、 {PtCl(SPh)(AsPh3)(PBu3)}
  参考文献：
  名称：

  Dinuclear platinum(II) complexes with a bridging mercapto group: X-ray crystal structure of a chloro/mercapto-bridged dimer

  摘要：

  [Pt2Cl2(mu-X)(mu-Y)(PR3)2] complexes [X = Cl, SPh; X = Y = SPh, Pr(i); PR3 = PBu3, PMe2Ph, PPh3, P(p-tol)3] have been prepared and characterized by elemental analysis, H-1 and P-31 NMR spectroscopy. Bridge cleavage reactions with various donor ligands have been investigated by P-31 {H-1} NMR. The X-ray crystal structure of [Pt2Cl2(mu-Cl) (mu-SEt)(PMe2Ph)2] is reported.

  DOI：

  10.1016/s0277-5387(00)86119-7

文献信息

• Preparation and characterization of aryltellurolato-bridged dinuclear complexes of platinum(II)
  作者：Vimal K. Jain、S. Kannan

  DOI：10.1016/0022-328x(91)80220-e

  日期：1991.11

  Complexes of the type [Pt2Cl2(μ-X)(μ-TeAr)(PR3)2] (X = Cl or TeAr; Ar = Ph, 4-MeC6H4, 4-MeOC6H4, 4-EtOC6H4; PR3 = PEt3, PnBu3 or PMe2Ph) and [Pt2(μ-TeAr)2(PC)2] (Ar = 4-MeC6H4, 4-MeOC6H4; PC = tBu2PCMe2CH2) have been prepared. These complexes were characterized by elemental analyses, and multinuclear NMR (1H, 13C, 31P, 125Te and 195Pt) spectroscopy. The stereochemistry of the complexes in solution

  该类型的复合物[PT 2氯2（μ-X）（μ-TEAR）（PR 3）2 ]（X = Cl或撕裂; Ar为pH值，4-MEC 6 ħ 4，4-MeOC 6 ħ 4， 4-EtOC 6 H ^ 4 ; PR 3 = PET 3，P ñ卜3或PME 2 PH）和[PT 2（μ-TEAR）2（PC）2 ]（AR = 4-MEC 6 ħ 4，4 -MeOC 6 H 4；PC= t Bu 2 PCMe 2CH 2）已经准备好。这些配合物的特征在于元素分析和多核NMR（1 H，13 C，31 P，125 Te和195 PT）光谱。溶液中配合物的立体化学已根据NMR数据进行了讨论。