| 138823-40-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 138823-40-2
• 化学式: C₄₆H₃₅As₂Cl₂O₃Ru
• 分子量: 957.601
• InChiKey: JPWYRQXEISAWDA-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  2-羟基-1,4-萘醌 、 trichlorobis(triphenylarsine)(methanol)ruthenium(III) 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  Complexes of lawsone with uranium, molybdenum, ruthenium and osmium, and their use as organic oxidants

  摘要：

  The new complexes trans-[UO2(NQ)2], cis-[MoO2(NQ)2] and [M(III)Cl2(EPh3)2 NQ] (M = Ru, E = As; M = Os, E = P; HNQ = lawsone, 2-hydroxyl-1,4-naphthoquinone) have been prepared. They were characterized by spectroscopic techniques and investigated by cyclic voltammetry. The complex [RuCl2(AsPh3)2NQ] was found to be a more efficient catalyst than that of the osmium complex for the oxidation of primary alcohols to aldehydes and of secondary alcohols to ketones in the presence of N-methylmorpholine-N-oxide as co-oxidant.

  DOI：

  10.1016/s0277-5387(00)86217-8