2-bromo-4-dodecylthiophene | 189102-86-1

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 芳基卤化物
• 英文名称: 2-bromo-4-dodecylthiophene
• 英文别名: Thiophene, 2-bromo-4-dodecyl-
• CAS: 189102-86-1
• 化学式: C₁₆H₂₇BrS
• 分子量: 331.36
• InChiKey: PAORRKMWCRYIMG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.8
• 重原子数：
  18
• 可旋转键数：
  11
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  28.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  benzo[1,2-d:4,5-d′]bis([1,2,3]thiadiazole) 、 2-bromo-4-dodecylthiophene 在 P(t-Bu)2Me*HBF₄ 、 palladium diacetate 、 potassium carbonate 、 三甲基乙酸 作用下， 以 甲苯 为溶剂， 反应 16.0h， 以20%的产率得到4,8-Bis(4-dodecylthiophen-2-yl)thiadiazolo[5,4-f][1,2,3]benzothiadiazole
  参考文献：
  名称：

  Semiconducting Compounds and Related Devices

  摘要：

  本教学涉及新的半导体化合物，其中包括一个或多个由公式（I）表示的基团，其中X是硫族元素; 以及一个或多个线性共轭基团和/或一个或多个不同于公式（I）所表示的基团的环状共轭基团。这些化合物可以用于制备薄膜半导体元件，这些元件可以集成到各种电子、光学和光电器件中。

  公开号：

  US20170110666A1

文献信息

• METHOD FOR MANUFACTURING CONJUGATED AROMATIC COMPOUND
  申请人：Oda Seiji

  公开号：US20110275859A1

  公开（公告）日：2011-11-10

  A method for manufacturing a conjugated aromatic compound comprising reacting an aromatic compound (A) wherein one or two leaving groups selected from the group consisting of an iodine atom, a bromine atom and a chlorine atom are bonded to an aromatic ring and the aromatic compound (A) does not have (c1) a group represented by the following formula (10): wherein A 1 represents a C1-C20 alkoxy group etc.; (g1) a C1-C20 alkyl group which may be substituted with a fluorine atom etc.; and (h1) a C2-C20 acyl group which may be substituted with a fluorine atom etc., at the neighboring carbon atom to the carbon atom to which the leaving group is bonded, with an aromatic compound (A) having the same structure as that of the above-mentioned aromatic compound (A) or an aromatic compound (B) wherein the aromatic compound (B) is structurally different from the above-mentioned aromatic compound (A), one or two leaving groups selected from the group consisting of an iodine atom, a bromine atom and a chlorine atom are bonded to an aromatic ring and the aromatic compound (B) does not have the above-mentioned (c1), (g1) and (h1) at the neighboring carbon atom to the carbon atom to which the leaving group is bonded, in the presence of (i) a nickel compound, (ii) a metal reducing agent, (iii) at least one ligand (L1) selected from the group consisting of a 2,2′-bipyridine compound having at least one electron-withdrawing group and having no substituent at 3-, 6-, 3′- and 6′-positions, and a 1,10-phenanthroline compound having at least one electron-withdrawing group and having no substituent at 2- and 9-positions, and (iv) at least one ligand (L2) selected from the group consisting of a 2,2′-bipyridine compound having at least one electron-releasing group and having no substituent at 3-, 6-, 3′- and 6′-positions, and a 1,10-phenanthroline compound having at least one electron-releasing group and having no substituent at 2- and 9-positions.

  一种制备共轭芳香化合物的方法，包括将含有一个或两个离去基团的芳香化合物（A）与含有相同结构的上述芳香化合物（A）或结构不同的芳香化合物（B）反应，其中这些离去基团选自碘原子、溴原子和氯原子，与芳香环结合，而芳香化合物（A）没有以下式（10）所代表的基团：其中A1代表C1-C20烷氧基等；（g1）代表C1-C20烷基基团，可能被氟原子等取代；以及（h1）代表C2-C20酰基基团，可能被氟原子等取代，与离去基团结合的碳原子的相邻碳原子处没有上述（c1）、（g1）和（h1），在（i）镍化合物、（ii）金属还原剂、（iii）从2,2′-联吡啶化合物和1,10-邻菲啰啉化合物中选择的至少一种配体（L1），具有至少一个吸电子基团且在3-、6-、3′-和6′-位置没有取代基，以及（iv）从2,2′-联吡啶化合物和1,10-邻菲啰啉化合物中选择的至少一种配体（L2），具有至少一个释电子基团且在3-、6-、3′-和6′-位置没有取代基团的情况下，在上述离去基团结合的碳原子的相邻碳原子处进行反应。
• US8598349B2
  申请人：——

  公开号：US8598349B2

  公开（公告）日：2013-12-03
• US9708346B2
  申请人：——

  公开号：US9708346B2

  公开（公告）日：2017-07-18
• Semiconducting Compounds and Related Devices
  申请人：Polyera Corporation

  公开号：US20170110666A1

  公开（公告）日：2017-04-20

  The present teachings relate to new semiconducting compounds including one or more moieties represented by formula (I): wherein X is a chalcogen; and one or more linear conjugated moieties and/or one or more cyclic conjugated moieties other than the moieties represented by formula (I). The present compounds can be used to prepare thin film semiconductor components which can be incorporated into various electronic, optical, and optoelectronic devices.

  本教学涉及新的半导体化合物，其中包括一个或多个由公式（I）表示的基团，其中X是硫族元素; 以及一个或多个线性共轭基团和/或一个或多个不同于公式（I）所表示的基团的环状共轭基团。这些化合物可以用于制备薄膜半导体元件，这些元件可以集成到各种电子、光学和光电器件中。