| 1632371-84-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 1632371-84-6
• 化学式: C₁₅H₁₉NO₃
• 分子量: 261.321
• InChiKey: WJRNPOPYSYHBSB-UKTHLTGXSA-N

反应信息

• 作为反应物：
  描述：

  在 三乙胺 、 三氯氧磷 作用下， 以 四氢呋喃 为溶剂， 反应 3.0h， 生成 (E)-4-(2-isocyanophenyl)hex-3-en-2-yl acetate
  参考文献：
  名称：

  Synthesis of 3,3-Disubstituted 2-Aminoindolenines by Palladium-Catalyzed Allylic Amidination with Isocyanide

  摘要：

  Synthesis of 3,3-disubstituted 2-aminoindolenines was achieved by palladium-catalyzed allylic amidination with an isocyanide. It was found that isocyanides are effective building blocks in palladium-catalyzed allylic functionalizations, analogous to carbon monoxide. This approach enables the direct construction of the indolenine ring along with the formation of a quaternary carbon and the introduction of an amino substituent in one step under mild conditions.

  DOI：

  10.1055/s-0033-1341241
• 作为产物：
  描述：

  、 乙酸酐 在 吡啶 作用下， 以 二氯甲烷 为溶剂， 反应 3.0h， 生成
  参考文献：
  名称：

  Synthesis of 3,3-Disubstituted 2-Aminoindolenines by Palladium-Catalyzed Allylic Amidination with Isocyanide

  摘要：

  Synthesis of 3,3-disubstituted 2-aminoindolenines was achieved by palladium-catalyzed allylic amidination with an isocyanide. It was found that isocyanides are effective building blocks in palladium-catalyzed allylic functionalizations, analogous to carbon monoxide. This approach enables the direct construction of the indolenine ring along with the formation of a quaternary carbon and the introduction of an amino substituent in one step under mild conditions.

  DOI：

  10.1055/s-0033-1341241