4,4'-(2,3-二氢噻吩并[3,4-b][1,4]二氧六环-5,7-二基)双[N,N-双(4-甲氧基苯基)苯胺] | 1622008-73-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 4,4'-(2,3-二氢噻吩并[3,4-b][1,4]二氧六环-5,7-二基)双[N,N-双(4-甲氧基苯基)苯胺]
• 中文别名: 4,4'-(2,3-乙烯基双氧噻吩-5,7-二基)双(N,N-双(4-甲氧苯基)苯胺)
• 英文名称: 2,5-bis(4,4’-bis(methoxyphenyl)aminophen-4’’-yl)-3,4-ethylenedioxythiophene
• 英文别名: 2,3,4,5-tetra[4,4’-bis(methoxyphenyl)aminophen-4“-yl]thiophene；2,5-bis(4,4’-bis(methoxyphenyl)aminophen-4”-yl)-3,4-ethylenedioxythiophene；4,4'-(2,3-Dihydrothieno[3,4-b][1,4]dioxine-5,7-diyl)bis[N,N-bis(4-methoxyphenyl)aniline]；4-[5-[4-(4-methoxy-N-(4-methoxyphenyl)anilino)phenyl]-2,3-dihydrothieno[3,4-b][1,4]dioxin-7-yl]-N,N-bis(4-methoxyphenyl)aniline
• CAS: 1622008-73-4
• 化学式: C₄₆H₄₀N₂O₆S
• 分子量: 748.899
• InChiKey: JOJPNOVYPGLCMM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11
• 重原子数：
  55
• 可旋转键数：
  12
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  90.1
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为产物：
  描述：

  4,4'-二甲氧基-4''-硼酸三苯胺 、 2,5-二溴-3,4-乙烯基二氧噻吩 在 四(三苯基膦)钯 、 potassium carbonate 作用下， 以 四氢呋喃 为溶剂， 反应 6.0h， 以1.3 g的产率得到4,4'-(2,3-二氢噻吩并[3,4-b][1,4]二氧六环-5,7-二基)双[N,N-双(4-甲氧基苯基)苯胺]
  参考文献：
  名称：

  [EN] HOLE TRANSPORTING MOLECULES AND THEIR USE IN SOLAR CELLS
  [FR] MOLÉCULES DE TRANSPORT DE TROUS ET LEUR UTILISATION DANS DES CELLULES SOLAIRES

  摘要：

  本发明涉及用于太阳能电池的空穴传输分子。具体而言，本发明涉及包含噻吩或双噻吩核心的这种空穴传输分子。

  公开号：

  WO2015084256A1

文献信息

• [EN] HOLE TRANSPORTING MOLECULES AND THEIR USE IN SOLAR CELLS<br/>[FR] MOLÉCULES DE TRANSPORT DE TROUS ET LEUR UTILISATION DANS DES CELLULES SOLAIRES
  申请人：UNIV NANYANG TECH

  公开号：WO2015084256A1

  公开（公告）日：2015-06-11

  The invention relates to hole transporting molecules for use in solar cells. In particular, present invention relates to such hole transporting molecules comprising thiophene or bithiophene cores.

  本发明涉及用于太阳能电池的空穴传输分子。具体而言，本发明涉及包含噻吩或双噻吩核心的这种空穴传输分子。
• Tertiary amine compound, photoelectric conversion element, and solar cell
  申请人：RICOH COMPANY, LTD.

  公开号：US10651390B2

  公开（公告）日：2020-05-12

  A tertiary amine compound is provided. The tertiary amine compound is represented by the following general formula (1): where each of Ar1 and Ar2 independently represents a benzene ring having an alkyl group or an alkoxy group, an unsubstituted benzene ring, a naphthalene ring having an alkyl group or an alkoxy group, or an unsubstituted naphthalene ring.

  提供了一种叔胺化合物。叔胺化合物由以下通式（1）表示： 其中 Ar1 和 Ar2 各自独立地代表具有烷基或烷氧基的苯环、未取代的苯环、具有烷基或烷氧基的萘环或未取代的萘环。
• TERTIARY AMINE COMPOUND, PHOTOELECTRIC CONVERSION ELEMENT, AND SOLAR CELL
  申请人：MATSUYAMA Tsuyoshi

  公开号：US20170358399A1

  公开（公告）日：2017-12-14

  A tertiary amine compound is provided. The tertiary amine compound is represented by the following general formula (1): where each of Ar 1 and Ar 2 independently represents a benzene ring having an alkyl group or an alkoxy group, an unsubstituted benzene ring, a naphthalene ring having an alkyl group or an alkoxy group, or an unsubstituted naphthalene ring.
• A Simple 3,4-Ethylenedioxythiophene Based Hole-Transporting Material for Perovskite Solar Cells
  作者：Hairong Li、Kunwu Fu、Anders Hagfeldt、Michael Grätzel、Subodh G. Mhaisalkar、Andrew C. Grimsdale

  DOI：10.1002/anie.201310877

  日期：2014.4.14

  AbstractWe report a novel electron‐rich molecule based on 3,4‐ethylenedioxythiophene (H101). When used as the hole‐transporting layer in a perovskite‐based solar cell, the power‐conversion efficiency reached 13.8 % under AM 1.5G solar simulation. This result is comparable with that obtained using the well‐known hole transporting material 2,2′,7,7′‐tetrakis(N,N‐di‐p‐methoxyphenylamine)‐9,9′‐spirobifluorene (spiro‐OMeTAD). This is the first heterocycle‐containing material achieving >10 % efficiency in such devices, and has great potential to replace the expensive spiro‐OMeTAD given its much simpler and cheaper synthesis.