catena-poly[[[tetraaquanickel(II)]-μ-4,4'-bipyridine-κ(2)N:N'] sulfate methanol solvate monohydrate] | 846547-13-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: catena-poly[[[tetraaquanickel(II)]-μ-4,4'-bipyridine-κ(2)N:N'] sulfate methanol solvate monohydrate]
• CAS: 846547-13-5
• 化学式: CH₄O*C₁₀H₁₆N₂NiO₄*H₂O*O₄S
• 分子量: 433.059
• InChiKey: JPELMVHVBXVURO-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  potassium disulphite 、 nickel(II) chloride hexahydrate 、 4,4'-联吡啶 以 甲醇 、 水 为溶剂， 生成 catena-poly[[[tetraaquanickel(II)]-μ-4,4'-bipyridine-κ(2)N:N'] sulfate methanol solvate monohydrate]
  参考文献：
  名称：

  An unusualP3₁2 framework for the Ni(4,4′-bipyridine)(H₂O)₄chain

  摘要：

  catena-Poly[[[tetraaquanickel(II)]-mu-4,4'-bipyridine-kappa(2)N:N'] thiosulfate dihydrate], {[Ni(C(10)H(8)N(2))(H(2)O)(4)]S(2)O(3).2H(2)O}(n), (I), and catena-poly[[[tetraaquanickel(II)]-mu-4,4'-bipyridine-kappa(2)N:N'] sulfate methanol solvate monohydrate], {[Ni(C(10)H(8)N(2))(H(2)O)(4)]SO(4).CH(4)O.H(2)O}(n), (II), are built up of {[Ni(4,4'-bipy)(H(2)O)(4)](2+)}(n) chains (4,4'-bipy is 4,4'-bipyridine) interwoven in an unusual P3(1) fashion. Voids are filled by the corresponding counter-anions and solvate molecules, defining a complex three-dimensional network surrounding them. In both structures, the cationic chains evolve around a set of twofold axes passing through the Ni(II) ions and bisecting the aromatic amines through their N (and their opposite C) atoms.

  DOI：

  10.1107/s0108270107007214