(3,3',5,5'-tetramethyl-4,4'-bipyrazole)(2,5-pyridinedicarboxylate)zinc(II) | 1174335-78-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: (3,3',5,5'-tetramethyl-4,4'-bipyrazole)(2,5-pyridinedicarboxylate)zinc(II)
• CAS: 1174335-78-4
• 化学式: C₇H₃NO₄*C₁₀H₁₄N₄*Zn
• 分子量: 420.743
• InChiKey: CWLNOWOZVDXTNZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -0.16
• 重原子数：
  27.0
• 可旋转键数：
  3.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  150.51
• 氢给体数：
  2.0
• 氢受体数：
  7.0

反应信息

• 作为产物：
  描述：

  zinc(II) sulfate heptahydrate 、 2,5-二吡啶羧酸 、 353'5'-四甲基-1H1'H-[44']联吡唑 以 水 为溶剂， 以80%的产率得到(3,3',5,5'-tetramethyl-4,4'-bipyrazole)(2,5-pyridinedicarboxylate)zinc(II)
  参考文献：
  名称：

  1D tubular and 2D roof-like coordination polymers based on [Zn(Pdc)] helices: Syntheses, structures and photoluminescence

  摘要：

  By parallel hydrothermal reactions of 2,5-pyridinedicarboxylic acid (2,5-H(2)Pdc) and 2,6-pyridinedicarboxylic acid (2,6-H(2)Pdc) with 3.3',5,5'-tetramethyl-4.4'-bipyrazole (Bpz) and ZnSO4 center dot 7H(2)O, two novel zinc coordination polymers, [Zn(Bpz)(2,5-Pdc)](n) (1) and [Zn-2(Bpz)(2,6-Pdc)(2)](n) (2), which contain in situ formed [Zn(Pdc)](n) helices as building blocks and exhibit photoluminescent at room temperature, were synthesized respectively. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2008.06.004