[lead(II)(2-pyridinecarboxylate)(azide)(H2O)] | 1224172-53-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [lead(II)(2-pyridinecarboxylate)(azide)(H2O)]
• CAS: 1224172-53-5
• 化学式: C₆H₄NO₂*H₂O*N₃*Pb
• 分子量: 389.339
• InChiKey: QEVJJIYUVHVRDD-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.89
• 重原子数：
  14.0
• 可旋转键数：
  1.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  143.22
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  [lead(II)(2-pyridinecarboxylate)(azide)(H2O)] 以 neat (no solvent) 为溶剂， 生成 lead(II) oxide
  参考文献：
  名称：

  Sonochemical syntheses of strawberry-like nano-structure mixed-ligand lead(II) coordination polymer: Thermal, structural and X-ray powder diffraction studies

  摘要：

  Nano-structure of a new Pb(II) two-dimensional coordination polymer, {[Pb(2-pyc)(N-3)(H2O)]n (1), 2-Hpyc = 2-pyridinecarboxylic acid} was synthesized by a sonochemical method. The new nano-structure was characterized by scanning electron microscopy, X-ray powder diffraction, IR spectroscopy and elemental analyses. Compound 1 was structurally characterized by single crystal X-ray diffraction and consists of two-dimensional polymeric units. The thermal stability of compound 1 was studied by thermal gravimetric and differential thermal analyses and compared. PbO nano-powder was obtained by calcination of the nano-structure of compound 1 at 400 degrees C. This study demonstrates the coordination polymers may be suitable precursors for the preparation of nano-scale materials and dependent on their packing they may produce different and interesting morphologies. (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.12.049
• 作为产物：
  描述：

  水 、 2-吡啶甲酸 、 lead(II) acetate trihydrate 、 sodium azide 以 水 为溶剂， 生成 [lead(II)(2-pyridinecarboxylate)(azide)(H2O)]
  参考文献：
  名称：

  Sonochemical syntheses of strawberry-like nano-structure mixed-ligand lead(II) coordination polymer: Thermal, structural and X-ray powder diffraction studies

  摘要：

  Nano-structure of a new Pb(II) two-dimensional coordination polymer, {[Pb(2-pyc)(N-3)(H2O)]n (1), 2-Hpyc = 2-pyridinecarboxylic acid} was synthesized by a sonochemical method. The new nano-structure was characterized by scanning electron microscopy, X-ray powder diffraction, IR spectroscopy and elemental analyses. Compound 1 was structurally characterized by single crystal X-ray diffraction and consists of two-dimensional polymeric units. The thermal stability of compound 1 was studied by thermal gravimetric and differential thermal analyses and compared. PbO nano-powder was obtained by calcination of the nano-structure of compound 1 at 400 degrees C. This study demonstrates the coordination polymers may be suitable precursors for the preparation of nano-scale materials and dependent on their packing they may produce different and interesting morphologies. (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.12.049