Ru₃(CO)₉-(diphenylarsino)methane-tris(methylphenyl)phosphine | 1268395-85-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Ru₃(CO)₉-(diphenylarsino)methane-tris(methylphenyl)phosphine
• 英文别名: Ru₃(CO)₉-dpam-tris(methylphenyl)phosphine；carbon monoxide;diphenylarsanylmethyl(diphenyl)arsane;ruthenium;tris(4-methylphenyl)phosphane
• CAS: 1268395-85-2
• 化学式: C₅₅H₄₃As₂O₉PRu₃
• 分子量: 1331.97
• InChiKey: XBLVVQVQMWYVJQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.17
• 重原子数：
  70
• 可旋转键数：
  7
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  9
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为产物：
  描述：

  1,2-μ-{bis(diphenylarsino)methane-As,As'}-1,1,1,2,2,2,3,3,3,3-decacarbonyl-triangulo-triruthenium(0) 、 三对苯甲基膦 以 正己烷 为溶剂， 生成 Ru₃(CO)₉-(diphenylarsino)methane-tris(methylphenyl)phosphine
  参考文献：
  名称：

  Crystal Structure Characterization and Catalytic Application of Novel Route Prepared Ru₃(CO)₉ DPAM (Diphenyl Arsino Methane)-tri Phenyl Phosphine Derivatives

  摘要：

  Triruthenium dodecacarbonyl-Ru-3(CO)(12) based diphenylarsino methane-triphenyl phosphine derivatives, such as Ru-3(CO)(9)-dpam-tris (methyl phenyl) phosphine (1), Ru-3(CO)(9)-dpam-tris (methoxy phenyl) phosphine (2), and Ru-3(CO)(9)-dpam-tris (fluro phenyl) phosphine (3) are synthesized by two step modified method. The catalytic hydrogenation of cyclohexene, styrene, and phenyl acetylene, on above mentioned Ru-based organometallic catalysts, has been studied under high pressure hydrogen atmosphere. The high pressure hydrogenation of cyclohexene and phenyl acetylene on Complex (1-3), showed good catalytic activity under pressurized condition. Hydrogenation of cyclohexene on Complex (3) showed better (50-65%) conversion in the presence of toluene than hexane solvent. The effect of temperature, role of solvent, and pressure conditions have also been studied.

  DOI：

  10.1080/15533174.2013.791839