(2,4,9,11,16,18,23,25-octakis(dioctylaminosulfonyl)phthalocyaninato)cobalt(II) | 944272-08-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: (2,4,9,11,16,18,23,25-octakis(dioctylaminosulfonyl)phthalocyaninato)cobalt(II)
• CAS: 944272-08-6
• 化学式: C₁₆₀H₂₈₀CoN₁₆O₁₆S₈
• 分子量: 2999.6
• InChiKey: BXSVUIRFHNQUAW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  43.82
• 重原子数：
  201.0
• 可旋转键数：
  128.0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  404.58
• 氢给体数：
  0.0
• 氢受体数：
  22.0

反应信息

• 作为产物：
  描述：

  二正辛胺 、 [2,4,9,11,16,18,23,25-octakis(sulfonyl chloride)phthalocyaninato]cobalt(II) 以 丙酮 为溶剂， 以95%的产率得到(2,4,9,11,16,18,23,25-octakis(dioctylaminosulfonyl)phthalocyaninato)cobalt(II)
  参考文献：
  名称：

  Synthesis and properties of metal phthalocyanines based on disulfophthalic acid

  摘要：

  Octasulfo-substituted cobalt phthalocyaninate was synthesized from 3,5-disulfophthalic acid, and its ammonium salt was converted into the corresponding sulfonyl chloride by the action of chlorosulfonic acid. Treatment of the chlorosulfonyl-substituted phthalocyanine complex with aliphatic amines gave octaalkyl-sulfamoyl derivatives. The products were characterized by IR and electronic absorption spectra.

  DOI：

  10.1134/s1070363206080317