bis(p-(dimethylamino)phenylisonitrile)rhodium(II) acetate | 212895-75-5

• 分子结构分类: 有机化合物 - 碳氢化合物衍生物
• 英文名称: bis(p-(dimethylamino)phenylisonitrile)rhodium(II) acetate
• CAS: 212895-75-5
• 化学式: C₂₆H₃₂N₄O₈Rh₂
• 分子量: 734.373
• InChiKey: TXTDJTJYGOISJM-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dirhodium tetraacetate 、 4-异氰基-N,N-二甲基苯胺 以 乙醇 为溶剂， 生成 bis(p-(dimethylamino)phenylisonitrile)rhodium(II) acetate
  参考文献：
  名称：

  π-Back-Bonding in Bis(isonitrile) Complexes of Rhodium(II) Acetate:  Structural Analogs for Rhodium Carbenoids

  摘要：

  Rh-2(O2CCH3)(4). 2C=NC6H4R (R = (CH3)(2)N-(1), -H (2), -CF3 (3)) were synthesized and characterized by X-ray crystallography. The structures exhibited several common features: (i) a relatively short Rh-C bond (2.148(4) Angstrom (1), 2.133(4) Angstrom (2), and 2.122(4) Angstrom (3)), (ii) an inversion center between the two rhodium atoms, (iii) coplanar aryl rings, and (iv) a significant deviation from linearity in the Rh-C-N bond angle. Comparison to other rhodium carboxylate complexes indicates the presence of pi-back-bonding and by extension, pi-back-bonding in rhodium-carbenoid systems.

  DOI：

  10.1021/om980066r