[MnSO4(1,2-ethanediol)] | 61624-88-2

• 分子结构分类: 有机化合物
• 英文名称: [MnSO4(1,2-ethanediol)]
• 英文别名: [MnGlSO4]
• CAS: 61624-88-2
• 化学式: C₂H₆O₂*Mn*O₄S
• 分子量: 213.07
• InChiKey: ANWOAFSBJXTDSZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -2.37
• 重原子数：
  10.0
• 可旋转键数：
  1.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  120.72
• 氢给体数：
  2.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  [MnSO4(1,2-ethanediol)] 以 neat (no solvent) 为溶剂， 生成 manganese(II) sulfate
  参考文献：
  名称：

  Preparation and thermoanalytical and structural study of complexes of 1,2-ethanediol and manganese(II) sulfate

  摘要：

  Parent and mixed ligand complexes of manganese(II) ion were prepared with water, sulfate ion and 1,2-ethanediol as ligands. The IR spectra and the thermoanalytical curves of the complexes were recorded. Oxygen atoms bound by one or two coordinate bonds to the metal ion, or by hydrogen-bonds in the crystal, were observed. As for the water molecule, 'crystal' and 'monohydrate' type of 1,2-ethanediol molecules were found, depending on the type of binding of the oxygen atoms.

  DOI：

  10.1023/b:jtan.0000032268.74743.ec
• 作为产物：
  描述：

  乙二醇 、 硫酸锰水合物 以 乙醇 、 乙二醇 为溶剂， 生成 [MnSO4(1,2-ethanediol)]
  参考文献：
  名称：

  Preparation and thermoanalytical and structural study of complexes of 1,2-ethanediol and manganese(II) sulfate

  摘要：

  Parent and mixed ligand complexes of manganese(II) ion were prepared with water, sulfate ion and 1,2-ethanediol as ligands. The IR spectra and the thermoanalytical curves of the complexes were recorded. Oxygen atoms bound by one or two coordinate bonds to the metal ion, or by hydrogen-bonds in the crystal, were observed. As for the water molecule, 'crystal' and 'monohydrate' type of 1,2-ethanediol molecules were found, depending on the type of binding of the oxygen atoms.

  DOI：

  10.1023/b:jtan.0000032268.74743.ec

文献信息

• The synthesis, structure and magnetism studies of two manganese sulfates with a 3D zeolite GIS framework and 1D chain structure
  作者：Gen-Wu Ge、Zhi-Yuan Qi、Yu-Run Miao、Hong-Bin Du、Xiao-Zeng You

  DOI：10.1039/c2ce26441b

  日期：——

  Two manganese sulfates, [C2H6O2][MnSO4] (1) and [C4N2H12][Mn(SO4)2(H2O)] (2), were solvothermally synthesized in the presence of ethylene glycol and piperazine. Both compounds are constructed from 4-membered ring ladder chains made of MnO6 and SO4 units, with 1 displaying a 3D zeolite gismondine (GIS) framework and 2 possessing a 1D chain structure, respectively.

  两种硫酸锰化合物[C2H6O2][MnSO4] (1) 和[C4N2H12][Mn(SO4)2(H2O)] (2)在乙二醇和哌嗪的存在下通过溶剂热合成。两者都是由MnO6和SO4单元构成的4元环梯链构建而成，其中1显示出3D zeolitic gismondine (GIS) 构架，而2则具有1D链结构。