[Cu(2-[2'-carboxyphenylazo]-5,5-dimethyl-1,3-cyclohexanedione(-1H))2] | 841233-26-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Cu(2-[2'-carboxyphenylazo]-5,5-dimethyl-1,3-cyclohexanedione(-1H))2]
• CAS: 841233-26-9
• 化学式: C₃₀H₃₀CuN₄O₈
• 分子量: 638.136
• InChiKey: IYDAQNLSPFJIKE-WXIBIURSSA-L

反应信息

• 作为产物：
  描述：

  copper(II) nitrate trihydrate 、 2-[2'-carboxyphenylazo]-5,5-dimethyl-1,3-cyclohexanedione 在 LiOH*H₂O 作用下， 以 甲醇 、 水 为溶剂， 以76%的产率得到[Cu(2-[2'-carboxyphenylazo]-5,5-dimethyl-1,3-cyclohexanedione(-1H))2]
  参考文献：
  名称：

  Azo Complexes of Cu(II), Co(II), Ni(II), Cd(II), Th(IV), and UO₂(VI) Ions. Mixed‐Ligand Complexes, Pyrolysis Products and Biological Activity

  摘要：

  The reactions of azo ligand, 2-[2'-carboxyphenylazo]-5,5-dimethyl-1,3-cyclohexane-dione, (H2L), with the metal ion Cd(II), Cu(II), Ni(II), Co(II), Th(IV), or UO2(VI) in the presence of LiOH as a deprotonating agent, yielded binary mononuclear complexes. The binary Cu(II) complex reacts with the ligands 1,10-phenanthroline or 2-aminopyridine to form mixed-ligand complexes. All the binary complexes of Cd(II), Cu(II), And Ni(II) have octahedral configurations, while the Co(II) complex is square-planar. The binary complexes of Th(IV) and UO2(VI) have distorted dodecahedral geometries. The mixed-ligand complexes have octahedral configurations. Thermal studies on these complexes showed the possibility of obtaining new complexes pyrolytically, where the complexes decompose through several isolable as well as nonisolable intermediates during heating. The structures of all complexes and the corresponding thermal products were elucidated by elemental analyses, conductance, IR and electronic absorption spectra, magnetic moments, H-1 NMR and TG-DSC measurements as well as by mass spectroscopy. The ligand and some of the complexes were found to activate the enzyme pectinlyase.

  DOI：

  10.1081/sim-200026204