{(PMe2Ph)3Cl2Ir(H2O)}ClO4 | 106587-16-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: {(PMe2Ph)3Cl2Ir(H2O)}ClO4
• CAS: 106587-16-0
• 化学式: C₂₄H₃₅Cl₂IrOP₃*ClO₄
• 分子量: 795.039
• InChiKey: LDUVKMLKHZQAPT-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  {(PMe2Ph)3Cl2Ir(H2O)}ClO4 在 ammonia 作用下， 以 二氯甲烷 为溶剂， 以69%的产率得到aminotris(dimethyl(phenyl)-l5-phosphaneyl)iridium(VII) dichloride perchlorate
  参考文献：
  名称：

  A comparison of NH3, PH3, PH2, OH2 and SH as ligands in iridium(III) complexes

  摘要：

  The aqua complex trans,mer-[IrCl2(H2O)(PMe2Ph)3][ClO4] of known crystal structure contains a highly labile H2O ligand which is readily substituted. The corresponding ammonia and phosphine complexes trans,mer-[IrCl2(EH3)(PMe2Ph)3][ClO4] (E = N or P), synthesised from the aqua complex, are inert and have been structurally characterised and compared with the aqua species. The cationic complex containing PH3 is readily deprotonated, but not the one with NH3, to give the structurally characterised neutral complex trans,mer- [IrCl2(PH2)(PMe2Ph)3]. The Ir-PH3 bond is significantly shorter than the Ir-PH2 bond and there are clear conformational changes resulting from deprotonation. Replacement of H2O by H2S leads to spontaneous deprotonation and formation of trans,mer-[IrCl2(SH)(PMe2Ph)3] (crystal structure also reported). Analysis of the geometries of trans,mer-[IrCl2L(PMe2Ph)3][ClO4] (L = H2O, NH3 or PH3) and of trans,mer-[IrCl2X(PMe2Ph)3] (X = H, Cl, SH or PH2) has allowed the properties of these ligands, in particular their trans influences, to be assessed.

  DOI：

  10.1039/dt9930001093
• 作为产物：
  描述：

  mer-IrCl3(PMe2Ph)3 、 silver perchlorate 在 水 作用下， 以 水 、 丙酮 为溶剂， 生成 {(PMe2Ph)3Cl2Ir(H2O)}ClO4
  参考文献：
  名称：

  八面体铑（III）和铱（III）叔膦配合物的立体化学非刚性和卤化物交换产生的NMR聚结效应

  摘要：

  摘要水合阳离子mer-[MCl 2（H 2 O）（PMe 2 Ph）3] [ClO 4]中的PMe 2 Ph配体在NMR时间尺度上快速交换，从而在1 H和31 P NMR中聚结光谱。反式为PMe 2 Ph的H 2 O配体的解离导致五坐标中间体。据信，该中间体（M = Rh）参与了[RhCl 2（H 2 O）（PMe 2 Ph）3] [ClO 4]与mer-[RhCl 3（PMe 2 Ph）3]的快速反应。氯化物转移机制导致PMe 2 Ph配体完全交换。

  DOI：

  10.1016/s0020-1693(00)85289-5

文献信息

• Characterisation of three isomers of trans-[IrCl2(EMe2Ph)4]ClO4(E = P or As) each containing adjacent parallel phenyl rings
  作者：Antony J. Deeming、Simon Doherty、Jane E. Marshall、Nicholas I. Powell

  DOI：10.1039/c39890001351

  日期：——

  The major of three isomers of trans-[IrCI2(EMe2Ph)4]CIO4(E = P or As), identified by their low temperature 31P1H}, 13C1H}, and 1H n.m.r. spectra, corresponds to that found in the crystal (E = P) and each contains adjacent and parallel phenyl rings leading to 1H n.m.r. (phenyl) resonances as high-field as δ 5.7.

  反式-[IrCI 2（EMe 2 Ph）4 ] CIO 4（E = P或As）的三种异构体中的主要异构体，由其低温31 P 1 H}，13 C 1 H}和1 H鉴定nmr光谱，对应于晶体中的光谱（E = P），每个光谱均包含相邻且平行的苯环，导致1 H nmr（苯基）共振，其高场为δ5.7。
• Synthesis, structure and spectroscopy of heterometallic compounds containing linear AuCNM, AuNCM and MNCAuCNM chains of atoms (M = Rh OR Ir): Crystal structure of I{PMe2Ph)3Cl2Rh(μ-NC)}2Au][ClO4]·2CH2Cl2
  作者：Antony J. Deeming、Graeme P. Proud、Helen M. Dawes、Michael B. Hursthouse

  DOI：10.1016/s0277-5387(00)80374-5

  日期：1988.1
• Deeming, Anthony J.; Proud, Graeme P.; Dawes, Helen M., Journal of the Chemical Society, Dalton Transactions, 1986, p. 2545 - 2550
  作者：Deeming, Anthony J.、Proud, Graeme P.、Dawes, Helen M.、Hursthouse, Michael B.

  DOI：——

  日期：——
• Deeming, Antony J.; Proud, Graeme P.; Dawes, Helen M., Journal of the Chemical Society, Dalton Transactions, 1988, p. 2475 - 2482
  作者：Deeming, Antony J.、Proud, Graeme P.、Dawes, Helen M.、Hursthouse, Michael B.

  DOI：——

  日期：——