neopentyl glycol-bis-(4-methyl-3,4-epoxy-cyclohexanecarboxylate) | 744910-23-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧杂环己烷
• 英文名称: neopentyl glycol-bis-(4-methyl-3,4-epoxy-cyclohexanecarboxylate)
• 英文别名: 2,2-dimethyl-propane-1,3-diol-bis-(4-methyl-3,4-epoxy-cyclohexanecarboxylate)；2,2-Dimethylpropane-1,3-diyl bis(6-methyl-7-oxabicyclo[4.1.0]heptane-3-carboxylate)；[2,2-dimethyl-3-(6-methyl-7-oxabicyclo[4.1.0]heptane-3-carbonyl)oxypropyl] 6-methyl-7-oxabicyclo[4.1.0]heptane-3-carboxylate
• CAS: 744910-23-4
• 化学式: C₂₁H₃₂O₆
• 分子量: 380.481
• InChiKey: NZUCSNHVFFNRCL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  27
• 可旋转键数：
  8
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  77.7
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  neopentyl glycol-bis-(4-methyl-3-cyclohexenecarboxylate) 在 过氧乙酸 作用下， 以 丙酮 为溶剂， 以70%的产率得到neopentyl glycol-bis-(4-methyl-3,4-epoxy-cyclohexanecarboxylate)
  参考文献：
  名称：

  Active ray curable ink-jet composition, image forming method using the same, ink-jet recording apparatus, and triarylsulfonium salt compound

  摘要：

  一种活性紫外光固化喷墨墨水组合物，包括含有不在活性紫外光辐射下生成苯的光诱导酸发生剂的盐类和含有分子中含有氧杂环戊烷环的光聚合化合物。

  公开号：

  US20040244641A1

文献信息

• Cycloaliphatic polyepoxy compounds and preparation thereof
  申请人：Daicel Chemical Industries, Ltd.

  公开号：EP1873149A1

  公开（公告）日：2008-01-02

  Is disclosed a cycloaliphatic polyepoxy compound represented by following Formula (1): wherein Y represents a linkage group or a single bond; and HAS each represent hydrogen atom at the junction between cyclohexane ring and oxirane ring, and the cyclohexane rings may each further have one or more substituents in addition to the groups shown in the formula. The cycloaliphatic polyepoxy compound contains stereoisomers in such proportions as to have a ratio A/B of 1.8 or more, wherein "A" and "B" are integrated intensities of signals of protons at the junction between cyclohexane ring and oxirane ring as determined by 1H-NMR spectroscopy of the compound, in which "A" represents the integrated intensity of a signal observed at a lower magnetic field, and "B" represents the integrated intensity of a signal observed at a higher magnetic field.

  公开了一种由下式（1）表示的环状脂肪族多环氧化合物：其中，Y表示连接基团或单键；HAS分别表示在环己烷环和环氧环之间的连接处的氢原子，环己烷环除了式中所示的基团外，还可以有一个或多个取代基。所述环状脂肪族多环氧化合物包含立体异构体，其比例为A/B≥1.8，其中“A”和“B”是化合物的1H-NMR光谱测定下在环己烷环和环氧环之间的连接处的质子信号的积分强度，“A”表示在较低磁场下观察到的信号的积分强度，“B”表示在较高磁场下观察到的信号的积分强度。
• Polymerizable Actinic Radiation Curable Composition, Polymerization Method, Actinic Radiation Curable Ink and Image Formation Method, and Ink Jet Recording Apparatus and Epoxy Compound
  申请人：Sasa Nobumasa

  公开号：US20080107821A1

  公开（公告）日：2008-05-08

  A polymerizable actinic radiation curable composition comprising a photo-acid generating compound and an epoxy compound represented by Formula (1): wherein X represents a divalent group selected form the group consisting of —O—, —S—, —SO—, —SO 2 —, —CBr 2 —, —C(CBr 3 ) 2 —, and —C(CF 3 ) 2 —; R 1 to R 18 each independently represent a hydrogen atom, a halogen atom, a hydrocarbon group having 1-8 carbon atoms, provided that the hydrocarbon group may contain an oxygen atom or a halogen atom, or a substituted or unsubstituted alkoxy group having 1-8 carbon atoms.

  一种可聚合光致酸固化组合物，包括一种光酸发生化合物和一种由式（1）表示的环氧化合物：其中X代表从羟基、硫基、磺酸基、磺酸酯基、溴代基、三溴甲基代基和三氟甲基代基中选择的二价基团；R1至R18各自独立地表示氢原子、卤素原子、具有1-8个碳原子的碳氢基团，其中碳氢基团可能含有氧原子或卤素原子，或具有1-8个碳原子的取代或未取代的烷氧基团。
• RECOVERY METHOD AND REUSE METHOD OF OXO ACID CATALYST
  申请人：DAICEL CORPORATION

  公开号：US20160074856A1

  公开（公告）日：2016-03-17

  Provided is a method for easily and efficiently recovering an oxoacid catalyst without deterioration in reaction product yield and catalytic activity, where the oxoacid catalyst has been used in a reaction for oxidizing an organic compound with hydrogen peroxide, also provided is a method for producing an oxide in which an organic compound is oxidized with hydrogen peroxide using the oxoacid catalyst recovered by the method, to yield the corresponding oxide. A method according to the present invention recovers an oxoacid catalyst used in a reaction for oxidizing an organic compound with hydrogen peroxide in an aqueous/organic solvent two-phase system. The method includes Step 1 in which the pH in the reaction system is adjusted to 5.0 or higher so as to transfer the oxoacid catalyst to the aqueous phase, and the organic phase is removed.

  提供了一种方法，可以轻松高效地回收氧酸催化剂，而不会降低反应产物收率和催化活性。该氧酸催化剂已用于氧化有机化合物的反应中，使用过氧化氢。同时提供了一种方法，使用通过该方法回收的氧酸催化剂，将有机化合物与过氧化氢氧化，以产生相应的氧化物。本发明提供的方法在水/有机溶剂两相体系中回收用于氧化有机化合物的氧酸催化剂。该方法包括步骤1，将反应体系中的pH调整至5.0或更高，以将氧酸催化剂转移至水相，并去除有机相。
• ACTIVE RAY-CURABLE INKJET INK, METHOD FOR FORMING IMAGE USING SAME, AND INKJET RECORDER
  申请人：Konica Minolta Medical & Graphic, Inc.

  公开号：EP1792952A1

  公开（公告）日：2007-06-06

  An activated light curable inkjet ink comprising: a photo-initiator, photo-polymerizable compound dispersant and modified silicone oil, wherein, when 0.1 percent by mass of the modified silicone oil is added to said activated light curable inkjet ink containing no modified silicone oil, a surface tension at 25 °C is reduced by 0 through 3 mN/m.

  一种活化光固化喷墨墨水，包括：光引发剂、可光聚合的化合物分散剂和改性硅油，其中，当向不含改性硅油的所述活化光固化喷墨墨水中添加 0.1%（质量百分比）的改性硅油时，25 °C 时的表面张力降低 0.3 mN/m。
• ACTINIC LIGHT CURABLE INK JET INK SET, IMAGE FORMING METHOD USING THE SAME, AND INK JET RECORDING APPARATUS
  申请人：Konica Minolta Medical & Graphic, Inc.

  公开号：EP1803781A1

  公开（公告）日：2007-07-04

  An active ray curable ink-jet ink set comprising an active ray curable yellow ink, an active ray curable cyan ink, an active ray curable black ink, and further one or more of active ray curable color inks other than yellow, cyan and black, wherein each of the active ray curable yellow ink, the active ray curable cyan ink, the active ray curable black ink, and the active ray curable color inks other than yellow, cyan and black, contains a photo-polymerization initiator, a photo-polymerizable compound, a pigment, and a dispersing agent, which dispersing agent has an amine value and an acid value, and the acid value is higher than the amine value, and an average particle diameter of the pigment contained in the yellow ink is larger than the average particle diameter of the cyan ink and that of the black ink by 0.025 - 0.090 µm, and further the average particle diameter of the pigment contained in each of the color inks is 0.070 - 0.220 µm.

  一种活性射线固化喷墨墨水组，包括一种活性射线固化黄色墨水、一种活性射线固化青色墨水、一种活性射线固化黑色墨水，以及除黄色、青色和黑色以外的一种或多种活性射线固化彩色墨水，其中每种活性射线固化黄色墨水、活性射线固化青色墨水、活性射线固化黑色墨水，以及除黄色、青色和黑色以外的活性射线固化彩色墨水，都含有光聚合引发剂、光聚合化合物、颜料和分散剂、其中黄色油墨、青色油墨、黑色油墨以及除黄色、青色和黑色以外的其他颜色油墨都含有光聚合引发剂、可光聚合化合物、颜料和分散剂，分散剂具有胺值和酸值，且酸值高于胺值，黄色油墨中所含颜料的平均颗粒直径比青色油墨和黑色油墨的平均颗粒直径大 0.025 - 0.090 µm，而且每种彩色油墨所含颜料的平均颗粒直径为 0.070 - 0.220 µm。