tetrasulfonated bis(dianisylphosphino)butane | 935837-71-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tetrasulfonated bis(dianisylphosphino)butane
• 英文别名: DAPBTS
• CAS: 935837-71-1
• 化学式: C₃₂H₃₆O₁₆P₂S₄
• 分子量: 866.84
• InChiKey: FHNOXFNOAIDJCG-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  bis(norbornadiene)rhodium(l)tetrafluoroborate 、 tetrasulfonated bis(dianisylphosphino)butane 以 重水 为溶剂， 生成 [Rh(tetrasulfonated bis(dianisylphosphino)butane)(norbornadiene)][BF4]
  参考文献：
  名称：

  Rhodium(I) hydrogenation in water: Kinetic studies and the detection of an intermediate using 13C{1H} PHIP NMR spectroscopy

  摘要：

  The mechanism for hydrogenation of dimethylmaleate in water using cationic rhodium complexes with water-soluble bi-dentate phosphines has been investigated using kinetics and a novel method for the indirect detection of intermediates in catalytic hydrogenation reactions, whereby a late intermediate was detected. A mechanism is proposed involving fast, irreversible substrate binding followed by a rate-determining reaction with dihydrogen. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.08.042