[Cu(4-(2-pyridyl)-6-(3-pyridyl)-2-aminopyrimidine)Cl]n | 1011800-68-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 英文名称: [Cu(4-(2-pyridyl)-6-(3-pyridyl)-2-aminopyrimidine)Cl]n
• CAS: 1011800-68-2
• 化学式: C₁₄H₁₁N₅*Cl*Cu
• 分子量: 348.274
• InChiKey: CKEYOMDBHQZBME-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  2-amino-4-(2-pyridyl)-6-(3-pyridyl)pyrimidine 、 copper(II) choride dihydrate 以 水 为溶剂， 以45%的产率得到[Cu(4-(2-pyridyl)-6-(3-pyridyl)-2-aminopyrimidine)Cl]n
  参考文献：
  名称：

  Three 1D copper(I/II) complexes of 4,6-dipyridyl-2-aminopyrimidine: Effect of the ligand isomerism on the structural motif

  摘要：

  Three copper(I/II) complexes [Cu-2(HL1)(2)Cl](n) (1), [Cu(H(2)L2)Cl](n) (2), and [Cu-2(H(2)L3)Cl-2](n) (3) were synthesized by the reaction of CuCl2 center dot 2H(2)O with three isomers of 4,6-dipyridyl-2-aminopyrimidine: H(2)L1, H(2)L2, and H(2)L3 under hydrothermal conditions. Although in compounds 1-3, the three ligands all exhibit bridging coordination modes, the structures of the resultant 1D polymers are very different. This result indicates that the structural motif of compounds 1-3 could be directed by the ligand isomers. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2007.02.021